Selective hydrogenation of aromatics and olefins in hydrocarbon fractions
AssigneeAshland Oil, Inc.
InventorsStephen M. Kovach, George D. Wilson
Life of this patent
Estimating the term…
Abstract
Hydrocarbon fractions boiling between 180.degree. and 600.degree.F. and containing aromatics, olefins, and sulfur and nitrogen compounds are hydrogenated with a platinum-palladium catalyst to reduce the concentration of aromatics and olefins. The catalyst is prepared by saturating a porous inert carrier, preferably alumina, with an aqueous acid solution of chloroplatinic acid and palladium (ous) chloride in a specified mole ratio of platinum to palladium. The saturated carrier is subsequently dried, calcined and reduced.
Claims12
A method for hydrogenating a hydrocarbon fraction boiling between about 200.degree. and about 700.degree.F. and containing aromatic and olefinic components, comprising contacting said hydrocarbon fraction with hydrogen gas in the presence of a catalyst under conditions sufficient to cause hydrogenation of at least a portion of the aromatics and olefinics contained in said hydrocarbon fraction, said catalyst comprising about 0.2 to about 1 percent by weight each of platinum and palladium in a mole ratio of platinum to palladium of between about 1 to 2 and about 1 to 6 and prepared by:
- a. contacting an inert gamma alumina carrier with an aqueous acidic solution containing both chloroplatinic acid and palladium (ous) chloride in solution;
- b. drying the resultant mixture;
- c. calcining the dried mixture in an inert atmosphere at a temperature between about 842.degree. and about 1,022.degree.F;
- and
- d. reducing said dried mixture;
Dependencies are inferred from the claim text.