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US 3,940,446 AGranted
Dehydrogenation of alcohols
AssigneeUniversal Oil Products Company
InventorSamuel Kahn
Life of this patent
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Abstract
Dehydrogenating a primary or secondary alcohol to the corresponding aldehyde or ketone in a compound also containing a tertiary alcohol, with survival of said tertiary alcohol, by effecting the dehydrogenation at a temperature of about 200.degree. to about 350.degree.C. in a stirred suspension of dehydrogenation catalyst and high boiling inert liquid.
Claims6
A process for the continuous liquid phase dehydrogenation of a primary or secondary alcohol which also contains a tertiary hydroxy group said alcohol possessing the following formula:
- ##EQU2## where R and R.sub.1 are independently selected from the group consisting of alkyl, aryl, aralkyl and cycloalkyl, R.sub.2 , R.sub.3 and R.sub.4 are independently selected from the group consisting of hydrogen, alkyl, aryl, aralkyl and cycloalkyl, and n is an integer of from 0 to 10, to the corresponding aldehyde or ketone without loss of said tertiary hydroxy group, which comprises effecting said dehydrogenation at a temperature of from about 200.degree. to about 350.degree.C. under a vacuum of from about 40 to about 250 mm. Hg. in contact with a stirred suspension of an alcohol dehydrogenation catalyst comprising cupric oxide in a mineral oil having a normal boiling point above about 350.degree.C and an end boiling point within the range of from about 450.degree. to about 550.degree.C, and continuously recovering the aldehyde or ketone.
Dependencies are inferred from the claim text.