Process for making ethylene glycol
AssigneeUnion Carbide Corporation
InventorsWellington E. Walker, Jean B. Cropley
Life of this patent
Estimating the term…
Abstract
This invention is concerned with improving the ethylene glycol production capabilities of the metal carbonyl catalyzed reaction between carbon monoxide and hydrogen by conducting the reaction such that the ethylene glycol concentration in the reaction mixture is less than 5 gram moles per liter, preferably between about 0.4 to 5 gram moles per liter of reaction mixture and the molar formation ratio between ethylene glycol and methanol in the reaction mixture exceeds about 0.3. In a preferred embodiment, a continuous process is operated in such a manner that the concentration of ethylene glycol in the product mixture removed from the reactor is greater than the average concentration of ethylene glycol in the reactor.
Claims7
In the continuous process of producing ethylene glycol and methanol which comprises converting a mixture of a continuous feed of carbon monoxide and a continuous feed of hydrogen to produce ethylene glycol and methanol by contacting said mixture with a catalytic amount of rhodium in complex combination with carbon monoxide, at a temperature of between about 100.degree.C. to about 375.degree.C. and a pressure of between about 500 p.s.i.a. and about 50,000 p.s.i.a. sufficient to form said ethylene glycol and methanol, wherein the improvement comprises maintaining the concentration of ethylene glycol in the reaction mixture at less than about 5 gram moles per liter of reaction mixture from said reaction and maintaining the molar formation ratio between ethylene glycol and methanol in the reaction mixture in excess of about 0.3.
Dependencies are inferred from the claim text.