Oxidation of unsaturated amines
AssigneeMonsanto Company
InventorsJohn S. McConaghy, Jr., Dennis C. Owsley
Life of this patent
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Abstract
Oxidation of an unsaturated amine to an unsaturated nitrile is carried out in presence of cuprous chloride, a nitrogen base and a halide salt soluble in the nitrogen base.
Claims8
A process for the production of an unsaturated nitrile which comprises reacting an unsaturated amine having the formula ##EQU5## or phenyl--CH.sub.2 NH.sub.2 wherein R.sub.1, R.sub.2 and R.sub.3 represent hydrogen or a C.sub.1 to C.sub.4 alkyl group with molecular oxygen in the presence of cuprous chloride, a nitrogen base that is not oxidized under the reaction conditions and a halide salt which is soluble in the nitrogen base and is selected from alkali metal halides, alkaline earth metal halides, quaternary ammonium halides, and phosphonium halides, the relative proportions of cuprous chloride and halide salt being from 1:10 to 10:1, at a temperature of from 0.degree. to 200.degree.C. and at atmospheric pressure or above.
A process for the production of acrylonitrile or methacrylonitrile which comprises reacting allylamine or methallylamine with molecular oxygen in the presence of a solution in pyridine of cuprous chloride and a lithium halide selected from lithium chloride and lithium bromide, in a cuprous chloride to lithium halide ratio of from 10:1 to 1:10, at a temperature of from 0.degree. to 200.degree.C and at atmospheric pressure or above.
Dependencies are inferred from the claim text.