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US 3,940,417 AGranted
Quaternised benzofuranyl-benzimidazoles
AssigneeCiba-Geigy Corporation
InventorHans Schlaepfer
Life of this patent
Estimating the term…
Abstract
The invention relates to new quaternised benzofuranyl-benzimidazole derivatives which can be prepared by known methods. Said compounds are useful as optical brighteners for organic material.
Claims5
A benzofurane of the formula ##SPC28##
- wherein
- R.sub.1 denotes hydrogen or a lower alkyl group or together with R.sub.2 denotes a fused benzene radical,
- R.sub.2 denotes hydrogen, a lower alkyl or alkoxy group, chlorine, bromine, carboxyl, aminocarbonyl, sulphonic acid, aminosulphonyl, or together with R.sub.3 denotes a fused benzene radical,
- R.sub.3 denotes hydrogen, lower alkyl, alkoxy or together with R.sub.4 denotes a fused benzene radical,
- R.sub.4 denotes hydrogen, a lower alkyl group, chlorine or bromine,
- R.sub.5 denotes hydrogen, a lower alkyl group or phenyl,
- R.sub.6 denotes hydrogen, lower alkyl, lower alkoxy, chlorine, bromine, or phenyl,
- R.sub.7 is hydrogen,
- R.sub.8 denotes a lower alkyl group, a hydroxy-lower-alkyl group, cyanoethyl, phenyl which is unsubstituted or substituted by a chlorine, bromine, a lower alkyl or lower alkoxy group, or phenyl loweralkyl,
- R.sub.9 denotes a lower alkyl group, a hydroxy-lower-alkyl group, phenyl lower-alkyl which is unsubstituted or substituted by chlorine or lower alkoxy, or the --CH.sub.2 CN, -- CH.sub.2 CONH.sub.2 or --CH.sub.2 -COOR radical, wherein R represents alkyl with one to four carbon atoms, and
- X denotes halogen, lower alkylsulphonic acid or phenylsulphonic acid which is unsubstituted or substituted by lower alkyl.
8 more elements
A benzofurane of the formula ##SPC29##
- wherein
- R.sub.1 is hydrogen or taken together with R.sub.2 is a fused benzene radical,
- R.sub.2 is hydrogen, or chlorine,
- R.sub.3 is methyl or lower alkoxy,
- R.sub.4 is hydrogen or chlorine,
- R.sub.5 is hydrogen or methyl,
- R.sub.6 is hydrogen, methyl, chlorine, or methylsulphonyl,
- R.sub.7, r.sub.10, and R.sub.11 are hydrogen,
- R.sub.8 is methyl, phenyl, benzyl, or cyclohexyl, and
- R.sub.9 is methyl or benzyl.
7 more elements
Dependencies are inferred from the claim text.