Cross-linked cyanoacrylate adhesive compositions
AssigneeJohnson & Johnson
InventorWendell C. Overhults
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AssigneeJohnson & Johnson
InventorWendell C. Overhults
Estimating the term…
New polymerizable adhesive compositions comprising a monomeric ester of .alpha.-cyanoacrylic acid and a difunctional monomeric cross-linking agent which is a diester of acrylic or methacrylic acid and an alcohol having at least two esterifiable hydroxyl group, are found to develop increased cohesive bond strength upon polymerization. The compositions, if desired, can contain a finely divided aggregate, preferred aggregates being alumina and quartz. In addition, the compositions can advantageously contain sodium fluoride. The monomeric compounds of these adhesive compositions are polymerized in a cross-linked mode by means of an amine activated free radical initiator. The compositions can be applied to either wet or dry surfaces of a variety of materials. They are suitable for application to animal tissue, e.g., bone and flesh, and are particularly suitable for the treatment of teeth, such as for use as temporary fillings, the preparation of dental restorations and especially for filling and sealing pits and fissures in prophylactic dentistry.
An adhesive composition comprising a cement portion and a catalyst portion, the cement portion comprising from 5 to 95% by weight of a monomeric ester of an .alpha.-cyanoacrylic acid and from 95 to 5% by weight of a difunctional monomer diester of an acid from the group consisting of acrylic and methacrylic acid and a polyfunctional alcohol having at least two esterifiable hydroxy groups, and the catalyst portion comprising from about 2 to 15 parts by weight of a free radical catalyst for each hundred parts by weight of the total cement portion, and an amine activator therefor in the amount of from 5 to 150 mole percent of the free radical catalyst.
A system for obtaining a hard cohesive crosslinked mass having distributed between a first component and a second component thereof a cement portion comprising from 5 to 95% by weight of a monomeric ester of an .alpha.-cyanoacrylic acid and from 95 to 5% by weight of a difunctional monomer diester of an acid from the group consisting of acrylic and methacrylic acid and a polyfunctional alcohol having at least two esterifiable hydroxy groups, and a catalyst portion comprising a free radical catalyst in the amount of from 2 to 15 parts by weight for each hundred parts by weight of the total cement portion, and an amine activator in the amount of from 5 to 150 mole percent of the free radical catalyst wherein all the amine activator is in the first component, and all the monomeric ester of the .alpha.-cyanoacrylic acid is in the second component.
Dependencies are inferred from the claim text.