Solubilizing process for oil insoluble pesticides
AssigneeTexaco Inc.
InventorsFrederic C. McCoy, Carl Loyal W. Swanson, deceased
Life of this patent
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Abstract
This invention concerns a process for converting normally oil-insoluble, nitrogen-containing pesticidal compounds to oil-soluble complexes by treatment with alkylated phenols, and to the oil-soluble complexes resulting therein.
Claims5
A process for converting normally paraffinic oil-insoluble 5,6-dihydro-2-lower alkyl-1,4-oxathiin-3-carboxanilide-4,4-dioxide pesticides, wherein said lower alkyl radical contains 1 to 4 carbon atoms, to their oil-soluble form by:
- a. admixing each mole of said compounds to be converted to their oil-soluble form with:
- b. a molar excess of at least one alkylated phenol wherein the alkyl groups contain from 3 to 30 carbon atoms, at temperatures ranging from 20.degree.C to 100.degree.C until said normally paraffinic oil-insoluble compounds are converted to their paraffinic oil-soluble form.
A process for converting the normally paraffinic oil-insoluble pesticide 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxanilide-4,4-dioxide to its paraffinic oil-soluble concentrated form, consisting essentially of admixing each part by weight of said paraffinic oil-insoluble compound to be solubilized with from 1 to 20 parts by weight of at least one alkylated phenol wherein the alkyl groups contain from 3 to 30 carbon atoms, and 1 to 50 parts by weight of paraffinic oils having Saybolt viscosities at 100.degree.F from 30 to 400 seconds, while maintaining the temperature between about 20.degree. to 100.degree.C until said paraffinic oil-based concentrate is formed.
A paraffinic oil-soluble pesticide concentrate of 5,6-dihydro-2-methyl-1,4-oxathiin-3-carboxyanilide-4,4-dioxide pesticide, said concentrate consisting essentially of:
- a. from about 25 to 95 parts by weight of phenol alkylated with alkyl groups containing 6 to 20 carbon atoms, and
- b. from about 75 to 5 parts by weight of said pesticide.
Dependencies are inferred from the claim text.