Hydrocarbon isomerization catalyst and process
AssigneeUniversal Oil Products Company
InventorJohn C. Hayes
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Abstract
A hydrocarbon isomerization catalyst composition, comprising a combination of catalytically effective amounts of a platinum or palladium component, an iridium component, a germanium component, a halogen component and a Friedel-Crafts metal halide component combined with a refractory inorganic oxide is disclosed. A specific example of the disclosed catalytic composition is a combination of catalytically effective amounts of a platinum component, an iridium component, a germanium component, a chloride component and an aluminum chloride component with an alumina carrier material, effective in isomerizing a pentane-hexane hydrocarbon fraction or in isomerizing non-equilibrium mixtures of alkylaromatic hydrocarbons such as xylenes.
Claims9
A catalytic composite consisting essentially of a refractory inorganic oxide having combined therewith, on a Friedel-Crafts metal halide-free basis, about 0.01 to about 2 weight percent platinum or palladium, about 0.01 to about 2 weight percent iridium, about 0.01 to about 5 weight percent germanium, and about 0.1 to about 3.5 weight percent halogen in halide form, calculated on an elemental basis, and about 1.0 to about 100 weight percent Friedel-Crafts metal halide, wherein the platinum or palladium, iridium and germanium are uniformly dispersed throughout the refractory inorganic oxide, wherein substantially all of the platinum or palladium and iridium are present in the corresponding metallic states and wherein substantially all of the germanium is present in the form of the oxide, sulfide, halide, oxychloride or aluminate.
Dependencies are inferred from the claim text.