Hydrocarbon conversion with a sulfided acidic catalytic composite
AssigneeUniversal Oil Products Company
InventorJohn C. Hayes
Life of this patent
Estimating the term…
Abstract
The performance of a hydrocarbon conversion process using a trimetallic acidic catalytic composite, comprising a combination of catalytically effective amounts of a platinum or palladium component, an iridium component, a nickel component, and a halogen component with a porous carrier material, is improved by sulfiding the catalytic component, prior to any contact with hydrocarbon and after substantially all of the metallic components have been reduced to the corresponding metallic states, so that about 0.01 to 1 wt. % sulfur is incorporated therein, thereby diminishing undesired exothermic demethylation and other hydrogenolysis reactions during the initial operation of the process and markedly increasing the over-all stability of the process.
Claims14
A process for catalytically reforming a gasoline fraction to produce a high octane reformate which comprises contacting the hydrocarbon at reforming conditions with a sulfided acidic catalytic composite comprising a porous carrier material containing, on an elemental basis, about 0.0l to about 2 wt. % platinum or palladium, about 0.01 to about 2 wt. % iridium, about 0.01 to about 5 wt. % nickel, about 0.1 to about 3.5 wt. % halogen, and about 0.01 to about 1 wt. % sulfur, wherein the platinum or palladium, iridium, and nickel are uniformly dispersed throughout the porous carrier material, wherein substantially all of the platinum or palladium, nickel, and iridium are present therein in a sulfided state or in the corresponding elemental metallic states, and wherein the composite is sulfided, prior to contact with the hydrocarbon and after substantially all of the platinum or palladium, iridium, and nickel contained therein have been reduced to the corresponding elemental metallic state, by treatment with a sulfiding gas at conditions selected to incorporate about 0.01 to about 1 wt. % sulfur.
Dependencies are inferred from the claim text.