Treatment of gases containing sulfur dioxide
AssigneeContinental Oil Company
InventorsEverett Gorin, Metro D. Kulik, Robert T. Struck
Life of this patent
Estimating the term…
Abstract
An improvement in regenerative SO.sub.2 scrubbing systems which use sodium, potassium or ammonium carbonate to react with the SO.sub.2 to form sulfite, wherein a thiosulfate-rich aqueous solution of the carbonate is used to prevent oxidation of the sulfite to sulfate; to serve both as a source of the carbonate and as a source of sulfite-reducing agent; and finally to increase the salt concentration in the SO.sub.2 absorbent solution, to thereby permit operation of the scrubbing system at higher temperatures than those normally employed.
Claims11
In a regenerative process for the removal of SO.sub.2 from an SO.sub.2 -containing gas stream which has (1) a scrubbing circuit containing a scrubbing zone through which a recirculating stream of aqueous sodium, potassium or ammonium carbonate solution continuously passes in intimate contact with said gas stream under sulfite-forming conditions to thereby convert the SO.sub.2 in the gas stream to sulfite, and (2) a regeneration zone for regenerating said carbonate for reuse in said scrubbing zone, the improvement which comprises
- a. maintaining in said recirculating aqueous solution, throughout its entire traverse around said scrubbing circuit, a thiosulfate having the same cation as said carbonate and in a concentration of at least 10 percent by weight of said recirculating solution;
- regulating the amount of sulfite in said recirculating aqueous solution so that its concentration is always less than 5 percent by weight thereof;
- c. converting the sulfite formed in said scrubbing zone to thiosulfate while in said scrubbing circuit, but in a sulfite-reduction zone separate from said scrubbing zone, by means of a sulfite-reducing agent;
- d. withdrawing a minor portion of said recirculating aqueous solution from said scrubbing circuit to a regeneration zone wherein thiosulfate contained in said minor portion is converted by means of CO to a mixture of carbonate and said sulfite-reducing agent;
- and
- e. returning an effluent aqueous stream containing in admixture said carbonate and said reducing agent to said scrubbing circuit.
A process for removing SO.sub.2 from a flue gas containing the same which comprises
- a. passing said flue gas through a gas scrubbing zone which is maintained at a temperature between about 120.degree. and 180.degree.F.;
- b. recirculating an aqueous solution through a circuit including said gas scrubbing zone, in intimate contact with said flue gas, said aqueous solution containing sodium, potassium or ammonium carbonate in at least sufficient amount to react with all the SO.sub.2 in the flue gas;
- c. maintaining in said recirculating aqueous solution, throughout its entire traverse around said circuit, a thiosulfate having the same cation as said carbonate and having a concentration of at least 10 percent by weight of said aqueous solution;
- d. regulating the amount of sulfite in said recirculating aqueous solution so that its concentration is always less than 5 percent by weight thereof;
- e. maintaining the pH of said recirculating aqueous solution leaving said scrubbing zone between 6 and 7.8;
- f. treating said recirculating aqueous solution after it leaves said scrubbing zone in its traverse around said circuit in a sulfite reduction zone which is separate from said scrubbing zone with a sulfide at reducing conditions to effect conversion of said sulfite to thiosulfate and substantially complete consumption of said sulfide;
- g. withdrawing a portion of said recirculating aqueous solution which is less than ten volume percent of said recirculating solution and conducting said portion to a regeneration zone;
- h. reacting a gas containing CO as the essential reductant in a regeneration zone with the thiosulfate contained in said withdrawn portion of said recirculating aqueous solution to yield an aqueous effluent product containing in admixture said carbonate and said sulfide;
- i. regulating the volume of said withdrawn portion to provide sufficient thiosulfate for the production of the requisite quantities of said carbonate and said sulfide;
- and
- j. returning said aqueous effluent product from said regeneration zone to said circuit to provide both the requisite carbonate for step (b) and the sulfide for step (f).
Dependencies are inferred from the claim text.