Low-temperature synthesis of urea

A process for separating a mixture of urea and ammonium chloride produced in high yield with a low level of impurities by combining as reactants phosgene and ammonia at a temperature in the range of about -50.degree.C to about -20.degree.C by adding one reactant to the other and maintaining the mixture in said temperature range, then combining said mixture and methanol, dissolving said urea in said methanol and separating the resulting solution of urea from the relatively insoluble ammonium chloride.