Novel odorant
AssigneeGivaudan SA
InventorPeter Naegeli
Life of this patent
Estimating the term…
Abstract
Novel compounds of formula ##SPC1## Wherein R.sup.1 represents a lower alkenyl group or R.sup.11, or taken together with R.sup.4 an oxo group; R.sup.11 represents hydrogen or a lower alkyl group; R.sup.2 represents hydrogen or a lower alkyl group; R.sup.3 represents methyl or methylene; R.sup.4 represents hydroxy or a loweralkoxy, lower alkenyloxy, loweralkoxyloweralkyl or acyloxy group and R.sup.5 represents hydrogen or, when simultaneously R.sup.3 represents methyl and R.sup.1 represents R.sup.11, taken together with R.sup.4 a 3.alpha., 6-epoxide group, and 1,8a-dihydro-derivatives of compounds of formula I wherein R.sup.3 represents methyl and R.sup.5 represents hydrogen. The use of said compounds as odorants and also processes for their preparation are disclosed.
Claims5
A compound of the formula ##SPC19##
- wherein
- R.sup.2 represents hydrogen or lower alkyl and
- R.sup.11 represents hydrogen or lower alkyl.
A process for the production of a compound having the formula ##SPC20##
- wherein R.sup.2 and R.sup.11 each represents hydrogen or a lower alkyl group, which comprises cyclising a 3-isopropenyl-1-methyl-1-cyclopentene having the general formula ##SPC21##
- in an organic solvent and in the presence of a Lewis acid.
3a,6-Epoxy-1,4,6-trimethyl-2,3,3a,4,5,6,7,8-octahydroazulene.
3a,6-Epoxy-7-isopropyl-1,4-dimethyl-2,3,3a,4,5,6,7,8-octahydroazulene.
3a,6-Epoxy-1,4-dimethyl-2,3,3a,4,5,6,7,8-octahydroazulene.
Dependencies are inferred from the claim text.