Fogged, direct positive silver halide emulsions containing a bleach inhibiting compound and a Dmin maintainer compound
AssigneeE. I. Du Pont de Nemours and Company
InventorsLeewellyn C. Fischer, Heman Dowd Hunt
Life of this patent
Estimating the term…
Abstract
Direct positive silver halide materials based on the Herschel effect having substantially reduced sensitivity to room light exposure contain a heterocyclic compound to prevent white light bleaching along with a second heterocyclic compound to prevent latent image formation due to white light exposure.
Claims4
In a Herschel reversal type direct positive silver halide emulsion having prefogged silver halide grains containing a desensitizing dye, the improvement comprising a combination of a bleach inhibiting compound which retards bleaching of fogging nuclei by short wavelength radiation and a different Dmin maintainer compound which inhibits residual latent image formation said bleach inhibiting compound being selected from the group consisting of 5-nitrobenzotriazole, 5-chlorobenzotriazole, 6-amino-2-(methylthio)-benzothiazole, 6-methyl-2-(p-amino-phenyl)-benzothiazole, 2-amino-6-methylbenzothiazole, 2-amino-6-methoxybenzothiazole, 2-amino-5,6-dimethylbenzothiazole, 6-amino-2-methyl-7-nitrobenzothiazole, 6-amino-4-mercaptobenzothiazole, 2-amino-5-nitrothiazole, 2-aminothiazole, 2-amino-4-methylthiazole, 2-amino-4,5-dimethylthiazole, 2-amino-5-(p-nitrophenyl-sulfonyl)-thiazole, 2-acetaminothiazole, 2-amino-4-phenyl-5-ethylthiazole, 2-amino-4-(chloromethyl) thiazole-HCl, 2-amino-5-nitrothiazole, 2,4-dihydroxythiazole-5-acetic acid, 2-amino-5-bromothiazole, 2-amino-5-ethyl-4-phenyl-oxazole, 4-amino-6-chloro-5-nitropyridine, 5-aminoindiazole, 4-benzoylimino-3-t-butyl-1,3-thiazilidine-2-thione, 4-benzoylimino-3-phenyl-1,3-thiazilidine-2-thione, and said Dmin maintainer compound being selected from the group consisting of 2-amino-5-nitropyridine, 2-amino-4-methyl-2-nitropyridine, 2-amino-4-methyl-3-nitropyridine, 2-amino-3-nitropyridine, pyromellitimide, 5-nitroindazole, 6-nitroindazole, 3-chloro-5-nitroindazole, 3-chloro-6-nitroindazole, 5-nitrobenzotriazole, 6-chlorobenzotriazole, benzotriazole, 3-amino-1H-1,2,3,-triazole, 2-amino-5-nitrothiazole, 2-methyl-6-nitrobenzothiazole, 2-mercapto-6-nitrobenzothiazole, 2-acetamido-5-(p-nitrophenylmercapto)-thiazole, 6-amino-2-methyl-7-nitrobenzothiazole, 2-amino-5-chlorobenzoxazole, 2-nitrothiophene, 5-nitrobenzimidazole, 5-nitro-2-benzimidazole-thiol, 8-nitro-quinoline, m-nitrobenzamidine, 5-nitroanthraquinone sulfonic acid and p-nitrobenzenediazonium fluoborate.
Dependencies are inferred from the claim text.