Adhesion of olefin copolymer rubber to nylon textile
AssigneeUniroyal, Inc.
InventorsStephen E. Cantor, Arthur A. Blaskiewicz
Life of this patent
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Abstract
Halogenated olefin copolymer rubber, particularly halogenated EPDM (prepared by heating the rubber in admixture with an N-haloamide [e.g., 1,3-dichloro-5,5-dimethyl hydantoin or N,N'-dichloro-p-toluene sulfonamide]) is blended with curatives (sulfur, accelerator) and a resorcinol-aldehyde condensation product in which the aldehyde has 2-4 carbon atoms (e.g., acetaldehyde) to make a vulcanizable adhesive for nylon textile. Nylon fabric coated with the composition is useful for making air bags (passive restraints for automotive vehicles). The adhesive is also useful for making nylon-reinforced tires, hose, etc.
Claims8
An adhesive composition, which adheres firmly to nylon fabric when vulcanized in contact therewith, comprising a mixture of
- A. a reaction product of an elastomeric terpolymer consisting of ethylene, propylene and a copolymerizable non-conjugated diene with from 0.05 to 15 parts, per 100 parts by weight of the said terpolymer, of an N-haloamide selected from the group consisting of N-halomonoamides of formula I, N-halohydantoins of formula II, N-halosuccinimides of formula III, N-haloglycolurils of formula IV and trihaloisocyanuric acids of formula V, as follows:
- ##EQU4## wherein R.sup.1 is selected from the group consisting of alkyl having 1 to 8 carbon atoms and cycloalkyl having 5 to 8 carbon atoms, R.sup.2 is selected from the group consisting of hydrogen, alkyl having 1 to 10 carbon atoms, aralkyl having 7 to 10 carbon atoms and cycloalkyl having 5 to 8 carbon atoms, and X is selected from the group consisting of chlorine, bromine and iodine;
- ##EQU5## wherein R.sup.3 and R.sup.4 are the same or different and are as previously defined for R.sup.1 in formula I, and X.sup.1 and X.sup.2 are the same or different and are selected from the group consisting of hydrogen and halogen provided that at least one of them is halogen, said halogen being selected from the group consisting of chlorine, bromine and iodine;
- ##EQU6## wherein R.sup.5 and R.sup.6 are the same or different and are as previously defined for R.sup.1 in formula I, or may be alkylene having 1 to 4 carbon atoms joined directly together or through a chain of up to 4 methylene groups, and X is as previously defined for formula I;
- ##SPC6##
- wherein R.sup.7 and R.sup.8 are the same or different and are hydrogen or as previously defined for R.sup.1 in formula I, and X.sup.3, X.sup.4, X.sup.5 and X.sup.6 are the same or different and are selected from the group consisting of hydrogen and halogen provided that at least one of them is halogen, said halogen being selected from the group consisting of chlorine, bromine and iodine;
- and ##SPC7##
- wherein X.sup.7, X.sup.8 and X.sup.9 are the same or different and are halogen selected from the group consisting of chlorine, bromine and iodine,
- with (B) from 0.2 to 10 parts, per 100 parts by weight of the said terpolymer, of a resorcinol-alkyl aldehyde condensation product wherein the aldehyde contains from 2 to 4 carbon atoms, said condensation product being made by condensation, in alcoholic or aqueous medium in the presence of an acid catalyst at a temperature up to reflux temperature, of from 1/2 to 1 mole of said aldehyde per mole of resorcinol.
An adhesive composition which adheres firmly to nylon fabric when vulcanized in contact therewith comprising, in admixture,
- a. an elastomeric terpolymer of ethylene, propylene, and a copolymerizable non-conjugated diene, said terpolymer being halogenated by heating in admixture with from 0.1 to 10 parts, per 100 parts by weight of the terpolymer, of an N-haloamide at a temperature of from 200.degree. to 350.degree.F. for a period of from 1 to 5 minutes to effect halogenation of the terpolymer;
- b. from 0.5 to 5 parts, per 100 parts by weight of the terpolymer, of a resorcinol-alkyl aldehyde condensation resin wherein the aldehyde contains from 2 to 4 carbon atoms, said condensation product being made by condensation, in alcoholic or aqueous medium in the presence of an acid catalyst at a temperature up to reflux temperature, of from 1/2 to 1 mole of said aldehyde per mole of resorcinol;
- and
- c. not more than 3 parts of sulfur, per 100 parts by weight of the terpolymer, as a curative for the said terpolymer.
Dependencies are inferred from the claim text.