Resinous laminates having improved gas permeation and resistance to delamination
AssigneeToyo Seikan Kaisha, Ltd.
InventorsSadao Hirata, Syunsaku Hirata, Toru Suzuki, Akira Kishimoto
Life of this patent
Estimating the term…
Abstract
A resin laminate structure comprising a layer of a polymer selected from the group consisting of polyolefins and saponified products of ethylene-vinyl acetate copolymers and a layer of a blend comprising (A) a polyolefin and (B) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 25 to 50 mole % and a degree of saponification of at least 96% at an A:B mixing weight ratio ranging from 98:2 to 2:98, said two layers being laminated so that they are adjacent to each other.
Claims17
A resin laminate structure comprising at least one layer (a) of a polyolefin and at least one layer (b) consisting essentially of (A) a polyolefin and (B) a saponified product of ethylene-vinyl acetate copolymers having an ethylene content of 25 to 50 mole % and a degree of saponification of at least 96% at an A :
- B mixing weight ratio ranging from 90 :
- 10 to 10 :
- 90, said two layers being laminated by means of co-extrusion without an adhesive so that said layer (a) and said layer (b) are adjacent to each other, wherein said layer (b) is of such a multi-layer laminar structure that the polymer composition is different with respect to the thickness direction but substantially identical with respect to the plane direction and that when the layer (b) is divided into at least two layers in the direction of the thickness, at least that divided layer adjacent to said layer (a) contains predominantly the polyolefin (A), namely contains said saponified product in an amount expressed by the following formula
- M.sub.2 = m.sub.2 X
- wherein X stands for the average content (% by weight) of the saponified product of the ethylene-vinyl acetate copolymer in the said layer (b), m.sub.2 is a number of from 0 to 0.95, and M.sub.2 is the content (% by weight) of said saponified product in said specific divided layer,
- and an adjacent divided layer contains predominantly the saponified product of the ethylene-vinyl acetate copolymer (B), namely contains the saponified product in an amount expressed by the following formula
- M.sub.1 = m.sub.1 X
- wherein X is as defined above, m.sub.1 is a number of at least 1.05, and M.sub.1 is the content (% by weight) of said saponified product in said specific divided layer.
A resin laminate structure comprising two surface layers of a polyolefin and an intermediate layer of a blend consisting essentially of (A) said polyolefin, (B) a saponified product of an ethylene-vinyl acetate copolymer having an ethylene content of 25 to 50 mole % and a degree of saponification of at least 96% and (C) a thermoplastic polymer containing a carbonyl group at the main or side chain thereof at a concentration of 120 to 1400 milliequivalents per 100 g of the polymer, the weight ratio of B :
- C being within 95 :
- 5 to 50 :
- 50, said polyolefin (A) being present in an amount of 5 to 100 parts by weight per 100 parts by weight of the sum of said polymers (B) and (C), and said two surface layers and said intermediate layer being laminated by means of co-extrusion without an adhesive so that said two surface layers and said intermediate layer are adjacent to each other, wherein said intermediate layer has such a multi-layer laminar structure that the polymer composition is different with respect to the thickness direction but substantially identical with respect to the plane direction and that when the intermediate layer is divided into three layers in the direction of the thickness, the two divided layers adjacent to said polyolefin surface layers each contain predominantly the polyolefin (A) and the carbonyl group-containing thermoplastic polymer (C), namely contain said saponified product (B) in an amount expressed by the following formula
- M.sub.1 = m.sub.1 X
- wherein X stands for the average content (% by weight) of the ethylene-vinyl acetate copolymer saponified product in the blend layer, m.sub.1 is a number of from 0 to 0.95, and M.sub.1 is the content (% by weight) of said saponified product in said divided outer layer,
- and the divided inner layer contains predominantly the ethylene-vinyl acetate copolymer saponified product (B), namely contains said saponified product (B) in an amount expressed by the formula
- M.sub.2 = m.sub.2 X
- wherein X is as defined above, m.sub.2 is a number of at least 1.05 and M.sub.2 is the content (% by weight of said saponified product in said divided inner layer.
Dependencies are inferred from the claim text.