Coal-anthracene oil slurry liquefied with carbon monoxide and barium-promoted catalysts
AssigneePhillips Petroleum Company
InventorArmin C. Pitchford
Life of this patent
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Abstract
A heavy hydrocarbon feedstock is upgraded by at least one of the processes of desulfurization, decreasing carbon residues, increasing API gravity, and liquefaction of solid feedstock by reacting the feedstock at elevated temperature and pressure in the presence of carbon monoxide and in the presence of a catalytically active metal. In one embodiment the active metallic catalyst is associated with minor amounts of alkali or alkaline earth metals to minimize promotion of cracking side reactions. In a preferred embodiment a heavy hydrocarbon feedstock is upgraded in the presence of the catalyst system formed from a barium salt which has been deposited on cobalt molybdate dispersed on an alumina support.
Claims7
A method for liquefying coal in which the coal is slurried in anthracene oil, said method comprising contacting said coal anthracene oil slurry with a catalytically active metal selected from the group consisting essentially of molybdenum, nickel, cobalt, and iron promoted with a barium compound in the presence of carbon monoxide at a temperature in the range of 675.degree. to 720.degree.F and a pressure in the range of about 1,000 to about 5,000 psig for a time sufficient to carry out the process of liquefaction of the coal.
Dependencies are inferred from the claim text.