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US 2026/0310075 A1Published application
Onium salt monomer, polymer, chemically amplified resist composition, and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorsRyo Sudo, Gentaro Hida, Miyu Yoshida
Life of this patent
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Abstract
The onium salt monomer can be used for a chemically amplified resist composition which is processed by photolithography using, in particular, high-energy radiation such as a KrF excimer laser beam, an ArF excimer laser beam, an electron beam (EB) or EUV. The onium salt monomer having the following formula (a).
Claims13
An onium salt monomer having the following formula (a):
- wherein m1 is 0 or 1, m2 is 0, 1, 2, 3 or 4 in case of m1=0, and 0, 1, 2, 3, 4, 5 or 6 in case of m1=1, m3 is 0, 1, 2, 3 or 4 in case of m1=0, and 0, 1, 2, 3, 4, 5 or 6 in case of m1=1, m2+m3 is from 0 to 4 when m1=0 and m2+m3 is from 0 to 6 when m1=1, m4 is 0 or 1, m5 is 1, 2, 3 or 4 when m4=0, and 1, 2, 3, 4, 5 or 6 when m4=1,
- RA is hydrogen atom or methyl,
- R1 is halogen exclusive of iodine, nitro group, hydroxy group, cyano group, a C1-C20 hydrocarbyl group which may contain a heteroatom, a C1-C20 hydrocarbyloxy group which may contain a heteroatom, or a C1-C20 hydrocarbylthio group which may contain a heteroatom, a plurality of R1 may be identical or different and a plurality of R1 may bond together to form a ring with the carbon atoms to which they are attached, when m3 is 2 or more,
- R2 is halogen exclusive of iodine, or an electron withdrawing group, a plurality of R2 may be identical or different and a plurality of R2 may bond together to form a ring with the carbon atom to which they are attached, when m5 is 2 or more, except that all R2 is fluorine,
- LA, LB, LC and LD are each independently a single bond, ester bond, ether bond, amide bond, sulfonic ester bond, sulfonic amide bond, carbonate bond or carbamate bond,
- X1 and X2 are each independently a single bond, or a C1-C40 hydrocarbylene group which may contain a heteroatom,
- Z+ is a sulfonium cation having the following formula (Z-1) or an iodonium cation having the following formula (Z-2);
- wherein Rct1 to Rct5 are each independently halogen, or a C1-C30 hydrocarbyl group which may contain a heteroatom, and Rct1 and Rct2 may bond together to form a ring with the sulfur atom to which they are attached.
5 more elements
Dependencies are inferred from the claim text.