US 2026/0308453 A1Published application

Polymerizable liquid crystal composition

AssigneeRolic Technologies AG

InventorsSabrina CHAPPELLET, Richard FRANTZ

Life of this patent

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Abstract

A polymerizable liquid crystal composition comprising (i) a polymerizable liquid crystal compound capable of exhibiting birefringence of reverse wavelength dispersibility when the polymerizable liquid crystal compound is in an oriented state, and (ii) a polymerization initiator, which is represented by the following formula (I) exhibits a favorable high temperature stability. A liquid crystal film, which may be obtained via curing of the polymerizable product, is useful in the manufacture of an optical device or an electro-optical device.

Claims15

Dependent claims

wherein
R1 is hydrogen, C1-C20-alkyl, C1-C6-alkyl-C3-C6-cycloalkyl, C3-C20-cycloalkyl, or C2-C12-alkenyl, wherein C3-C20-cycloalkyl or C2-C12-alkenyl is uninterrupted or interrupted by one or more O, S, CO, NR10 or COOR4;
or
R1 is C1-C20alkyl which is unsubstituted or substituted by one or more halogen, OR4, SR9, NR10R11, COOR4 CONR10R11, CN, PO(OR3a)2, S(O)m—R3a,
C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4, SR9, NR10R11, PO(OR3a)2 or S(O)m—R3a, or
R1 is C2-C20alkyl which is interrupted by one or more O, CO, S, C(O)O, OC(O), SO, SO2, phenylene, naphthylene or NR10, wherein the interrupted C2-C20alkyl is unsubstituted or substituted by one or more halogen, C3-C8cycloalkyl, OH, SH, OR4, SR9, COOR4, O(CO)—R3a, CONR10R11, NR10R11, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4, SR9 or NR10R11;
or
R1 is C6-C20aryl or C3-C20heteroaryl each of which is unsubstituted or substituted by one or more C1-C20alkyl, phenyl, halogen, C1-C4haloalkyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a, (CO)NR10R11, PO(OR3a)2, S(O)m—R3a or group
or by one or more C2-C20alkyl which is interrupted by one or more O, S, or NR10;
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4, CONR10R11, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, C6-C20aryloxycarbonyl, C3-C20heteroaryloxycarbonyl, OR4, SR9 or NR10R11;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4, SR9 or NR10R11;
or
R1 is C2-C20alkanoyl or benzoyl which is unsubstituted or substituted by one or more C1-C6alkyl, phenyl, OR4, SR9 or NR10R11;
or
R1 is C2-C12alkoxycarbonyl optionally interrupted by one or more —O— and/or optionally substituted by one or more hydroxyl groups;
or
R1 is phenoxycarbonyl which is unsubstituted or substituted by C1-C6alkyl, halogen, phenyl, OR4, SR9 or NR10R11;
or
R1 is CN, (CO)—R3a, COOR4, CONR10R11, NO2, PO(OR3a)2 or S(O)m—R3a;
R1a is hydrogen, C1-C20alkyl, CN, (CO)—R3a, COOR4a, CONR10aR11a, NO2, PO(OR3a)2 or S(O)m—R3a, or
R1a is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a, or
R1a is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R1a is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R1a is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a CONR10aR11a, PO(OR3a)2 or S(O)m—R3a, or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a;
R2 is hydrogen, C1-C20-alkyl or C1-C6-alkyl-C3-C6-cycloalkyl which is unsubstituted or substituted by one or more halogen, OR4, SR9, COOR4CONR10R11, NR10R11, PO(OR3a)2, COR3a, or
R2 is C2-C20alkyl or C1-C6alkyl-C3-C6-cycloalkyl which is interrupted by one or more O, CO, S, C(O)O, OC(O), SO, SO2, phenylene, naphthylene or NR10;
wherein the interrupted C2-C20alkyl is unsubstituted or substituted by one or more halogen, OR4, SR9, COOR4, CONR10R11, NR10R11;
or
R2 is C2-C4hydroxyalkyl, C2-C10alkoxyalkyl, C3-C8alkenyl, C3-C8cycloalkyl, phenyl-C1-C3alkyl, C2-C8alkanoyl, C3-C12alkenoyl, benzoyl;
or
R2 is C6-C20aryl or C3-C20heteroaryl each of which is unsubstituted or substituted by one or more C1-C12alkyl, C1-C4haloalkyl, phenyl, halogen, CN, NO2, OR4, SR9, NR10R11, (CO)—R3a, or by C2-C20alkyl which is interrupted by one or more O, S, or NR10, or each of which is substituted by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4, CONR10R11, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, C6-C20aryloxycarbonyl, C3-C20heteroaryloxycarbonyl, OR4, SR9 or NR10R11, or
R2 is a group
R3 is hydrogen or C1-C20-alkyl;
or
R3 is C1-C20alkyl substituted by one or more halogen, OR4, SR9, NR10R11, CN, COOR4, CONR10R11, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4, SR9 or NR10R11;
or
R3 is C1-C20alkyl interrupted by one or more O, S, NR10, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4, CONR10R11C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4, SR9 or NR10R11, or
R3 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10 or COOR4;
or
R3 is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a or SO2—R3a, or
R3 is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3 is C1-C20alkoxy, which is interrupted by one or more O, S, NR10, CO, SO or SO2;
or
R3 is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a or SO2—R3a, R3a is hydrogen or C1-C20-alkyl;
or
R3a is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a CONR10aR11a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a SR9a or NR10aR11a, or
R3a is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—(C1-C8alkyl), COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R3a is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a;
or
R3a is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3a is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3a is C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R3a is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3a is a group
R3b is hydrogen or C1-C20alkyl;
or
R3b is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a or NR10aR11a;
or
R3b is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—(C1-C8alkyl), COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R3b is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a;
or
R3b is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3b is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3b is C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R3b is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
R4 is hydrogen, (CO)—R3a, COOR4a, CO NR10aR11a, S(O)m—R3a or PO(OR3a)2;
or
R4 is C1-C20alkyl, which is substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a;
or
R4 is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a, or
R4 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R4 is C6-C20aryl, which is substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R4 is C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a, or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R4 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a,
R4a is hydrogen, C1-C20-alkyl, (CO)O(C1-C8-alkyl) or CON(C1-C8-alkyl)2;
or
R4a is C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R4a is C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R4a is C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8)2, phenyl or benzoyl;
R4a is C2-C12alkenyl, (CO)O(C1-C8alkenyl) or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R4a is C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
R5, R6, R7 and R8 independently of each other are hydrogen, C1-C20-alkyl, C6-C20-aryl, C1-C20-alkoxy, C6-C20-aryl C1-C20-alkyl, hydroxyl-C1-C20-alkyl, hydroxyl-C1-C20-alkoxy-C1-C20-alkyl, C3-C10-cycloalkyl, amino, CN, NO2, hydroxy,
(CO)—R3a OR4a or COOR4;
R9 is hydrogen or C1-C20alkyl;
or
R9 is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a, or
R9 is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R9 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R9 is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R9 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
R9a is hydrogen or C1-C20alkyl;
or
R9a is C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R9a is C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R9a is C2-C12alkenyl or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R9a is C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8)2, phenyl or benzoyl;
or
R9a is C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
R10 and R11 independently of each other are hydrogen, C1-C20-alkyl, S(O)m—R3a, O(CO)—R3a (CO)—R3a or CONR10aR11a, or
R10 and R11 independently of each other are C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a PO(OR3a)2 or S(O)m—R3a;
or
R10 and R11 independently of each other are C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a, or
R10 and R11 independently of each other are C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R10 and R11 independently of each other are C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a, or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R10 and R11 independently of each other are C1-C20alkoxy, which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl or C1-C8alkoxyphenyl;
or
R10 and R11 independently of each other are C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R10 and R11 independently of each other are C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C4haloalkyl, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a or SO2—R3a, or
R10 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4-haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or
R10 and R11 together with the N-atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4-haloalkyl, CN, phenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
R10a and R11a independently of each other are hydrogen, C1-C20alkyl, S(O)m—(C1-C8alkyl), O(CO)(C1-C8alkyl), (CO)(C1-C8alkyl), (CO)O(C1-C8alkyl) or CON(C1-C8alkyl)2;
or
R10a and R11a independently of each other are C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R10a and R11a independently of each other are C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R10a and R11a independently of each other are C2-C12alkenyl or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R10a and R11a independently of each other are C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8alkyl)2, phenyl or benzoyl;
or
R10a and R11a independently of each other are C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
or
R10a and R11a independently of each other are C1-C20alkoxy, which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl or C1-C8alkoxyphenyl;
or
R10a and R11a independently of each other are C1-C20alkoxy, which is interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2;
or
R10a and R11a independently of each other are C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C4haloalkyl, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, C1-C8alkoxy, C1-C8alkylsulfanyl, N(C1-C8alkyl)2, CO(OC1-C8alkyl), (CO)—(C1-C8alkyl) or SO2—(C1-C8alkyl);
or
R10a and R11a together with the N-atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or N(C1-C8alkyl), and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl, N(C1-C8alkyl)2, NO2, halogen, C1-C4haloalkyl, CN, phenyl or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or N(C1-C8alkyl);
R12 and R13 independently of each other are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or
R12 and R13 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
or
R12 and R13 are halogen, CN, OR4, SR9, SOR9, SO2R9 or NR10R11, wherein the substituents OR4, SR9 or NR10R11 optionally form 5- or 6-membered rings via the radicals R4, R9, R10 and/or R11 with one of the carbon atoms of the phenyl, naphthyl, benzoyl or naphthoyl group or that of the substituent R3a;
or
R12 and R13 together are a group wherein R14, R15, R16 and R17 independently of one another are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or R14, R15, R16 and R17 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
or R14, R15, R16 and R17 are halogen, CN, OR4, SR9 or NR10R11;
or
R12 and R13 together are a group
wherein R18 and R19 independently of each other are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or R18 and R19 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
m is 1 or 2;
and
Q is CO or a direct bond.

177 more elements

Dependencies are inferred from the claim text.

Facts

Application: 19/475,893Filed 10 Apr 2024
Priority: EP 23173022.712 May 2023
Published: 8 Oct 2026
Term ends: Not estimatedThe source records don’t support an estimate.

Classification5 codes

C09K 19/54
Characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles: additives…
C09K 19/3452
The heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms: pyrazine
C09K 19/3497
Having sulfur as hetero atom: the heterocyclic ring containing sulfur and nitrogen atoms
C09K 2019/0448
Characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group: the…

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Abstract

wherein
R1 is hydrogen, C1-C20-alkyl, C1-C6-alkyl-C3-C6-cycloalkyl, C3-C20-cycloalkyl, or C2-C12-alkenyl, wherein C3-C20-cycloalkyl or C2-C12-alkenyl is uninterrupted or interrupted by one or more O, S, CO, NR10 or COOR4;
or
R1 is C1-C20alkyl which is unsubstituted or substituted by one or more halogen, OR4, SR9, NR10R11, COOR4 CONR10R11, CN, PO(OR3a)2, S(O)m—R3a,
C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4, SR9, NR10R11, PO(OR3a)2 or S(O)m—R3a, or
R1 is C2-C20alkyl which is interrupted by one or more O, CO, S, C(O)O, OC(O), SO, SO2, phenylene, naphthylene or NR10, wherein the interrupted C2-C20alkyl is unsubstituted or substituted by one or more halogen, C3-C8cycloalkyl, OH, SH, OR4, SR9, COOR4, O(CO)—R3a, CONR10R11, NR10R11, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4, SR9 or NR10R11;
or
R1 is C6-C20aryl or C3-C20heteroaryl each of which is unsubstituted or substituted by one or more C1-C20alkyl, phenyl, halogen, C1-C4haloalkyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a, (CO)NR10R11, PO(OR3a)2, S(O)m—R3a or group
or by one or more C2-C20alkyl which is interrupted by one or more O, S, or NR10;
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4, CONR10R11, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, C6-C20aryloxycarbonyl, C3-C20heteroaryloxycarbonyl, OR4, SR9 or NR10R11;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4, SR9 or NR10R11;
or
R1 is C2-C20alkanoyl or benzoyl which is unsubstituted or substituted by one or more C1-C6alkyl, phenyl, OR4, SR9 or NR10R11;
or
R1 is C2-C12alkoxycarbonyl optionally interrupted by one or more —O— and/or optionally substituted by one or more hydroxyl groups;
or
R1 is phenoxycarbonyl which is unsubstituted or substituted by C1-C6alkyl, halogen, phenyl, OR4, SR9 or NR10R11;
or
R1 is CN, (CO)—R3a, COOR4, CONR10R11, NO2, PO(OR3a)2 or S(O)m—R3a;
R1a is hydrogen, C1-C20alkyl, CN, (CO)—R3a, COOR4a, CONR10aR11a, NO2, PO(OR3a)2 or S(O)m—R3a, or
R1a is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a, or
R1a is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R1a is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R1a is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a CONR10aR11a, PO(OR3a)2 or S(O)m—R3a, or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a;
R2 is hydrogen, C1-C20-alkyl or C1-C6-alkyl-C3-C6-cycloalkyl which is unsubstituted or substituted by one or more halogen, OR4, SR9, COOR4CONR10R11, NR10R11, PO(OR3a)2, COR3a, or
R2 is C2-C20alkyl or C1-C6alkyl-C3-C6-cycloalkyl which is interrupted by one or more O, CO, S, C(O)O, OC(O), SO, SO2, phenylene, naphthylene or NR10;
wherein the interrupted C2-C20alkyl is unsubstituted or substituted by one or more halogen, OR4, SR9, COOR4, CONR10R11, NR10R11;
or
R2 is C2-C4hydroxyalkyl, C2-C10alkoxyalkyl, C3-C8alkenyl, C3-C8cycloalkyl, phenyl-C1-C3alkyl, C2-C8alkanoyl, C3-C12alkenoyl, benzoyl;
or
R2 is C6-C20aryl or C3-C20heteroaryl each of which is unsubstituted or substituted by one or more C1-C12alkyl, C1-C4haloalkyl, phenyl, halogen, CN, NO2, OR4, SR9, NR10R11, (CO)—R3a, or by C2-C20alkyl which is interrupted by one or more O, S, or NR10, or each of which is substituted by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4, CONR10R11, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, C6-C20aryloxycarbonyl, C3-C20heteroaryloxycarbonyl, OR4, SR9 or NR10R11, or
R2 is a group
R3 is hydrogen or C1-C20-alkyl;
or
R3 is C1-C20alkyl substituted by one or more halogen, OR4, SR9, NR10R11, CN, COOR4, CONR10R11, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4, SR9 or NR10R11;
or
R3 is C1-C20alkyl interrupted by one or more O, S, NR10, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4, CONR10R11C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4, SR9 or NR10R11, or
R3 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10 or COOR4;
or
R3 is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a or SO2—R3a, or
R3 is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3 is C1-C20alkoxy, which is interrupted by one or more O, S, NR10, CO, SO or SO2;
or
R3 is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4, SR9, NR10R11, COOR4, (CO)—R3a or SO2—R3a, R3a is hydrogen or C1-C20-alkyl;
or
R3a is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a CONR10aR11a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a SR9a or NR10aR11a, or
R3a is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—(C1-C8alkyl), COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R3a is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a;
or
R3a is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3a is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3a is C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R3a is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3a is a group
R3b is hydrogen or C1-C20alkyl;
or
R3b is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a or NR10aR11a;
or
R3b is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—(C1-C8alkyl), COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R3b is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a;
or
R3b is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
or
R3b is C1-C20alkoxy, which is unsubstituted or substituted by one or more C1-C10alkyl, C1-C4haloalkyl, halogen, phenyl, C1-C20alkylphenyl or C1-C8alkoxyphenyl;
or
R3b is C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R3b is C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C20alkyl, C1-C4haloalkyl, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—(C1-C8alkyl) or SO2—(C1-C4haloalkyl);
R4 is hydrogen, (CO)—R3a, COOR4a, CO NR10aR11a, S(O)m—R3a or PO(OR3a)2;
or
R4 is C1-C20alkyl, which is substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a;
or
R4 is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a, or
R4 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R4 is C6-C20aryl, which is substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R4 is C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a, or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R4 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a,
R4a is hydrogen, C1-C20-alkyl, (CO)O(C1-C8-alkyl) or CON(C1-C8-alkyl)2;
or
R4a is C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R4a is C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R4a is C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8)2, phenyl or benzoyl;
R4a is C2-C12alkenyl, (CO)O(C1-C8alkenyl) or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R4a is C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
R5, R6, R7 and R8 independently of each other are hydrogen, C1-C20-alkyl, C6-C20-aryl, C1-C20-alkoxy, C6-C20-aryl C1-C20-alkyl, hydroxyl-C1-C20-alkyl, hydroxyl-C1-C20-alkoxy-C1-C20-alkyl, C3-C10-cycloalkyl, amino, CN, NO2, hydroxy,
(CO)—R3a OR4a or COOR4;
R9 is hydrogen or C1-C20alkyl;
or
R9 is C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a, PO(OR3a)2 or S(O)m—R3a, or
R9 is C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a;
or
R9 is C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R9 is C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a;
or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R9 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
R9a is hydrogen or C1-C20alkyl;
or
R9a is C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R9a is C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R9a is C2-C12alkenyl or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R9a is C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8)2, phenyl or benzoyl;
or
R9a is C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
R10 and R11 independently of each other are hydrogen, C1-C20-alkyl, S(O)m—R3a, O(CO)—R3a (CO)—R3a or CONR10aR11a, or
R10 and R11 independently of each other are C1-C20alkyl substituted by one or more halogen, OR4a, SR9a, NR10aR11a, CN, COOR4a, CONR10aR11a, PO(OR3a)2, S(O)m—R3a, C3-C8cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or by one or more C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl, C1-C4haloalkyl, CN, NO2, OR4a, SR9a, NR10aR11a PO(OR3a)2 or S(O)m—R3a;
or
R10 and R11 independently of each other are C1-C20alkyl interrupted by one or more O, S, NR10a, CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)—R3a, COOR4a, CONR10aR11a, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, OR4a, SR9a or NR10aR11a, or
R10 and R11 independently of each other are C2-C12alkenyl or C3-C20cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, NR10a or COOR4a, or
R10 and R11 independently of each other are C6-C20aryl or C3-C20heteroaryl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a CONR10aR11a, PO(OR3a)2, S(O)m—R3a or group
or by one or more C1-C20alkyl which is unsubstituted or substituted by one or more halogen, COOR4a, CONR10aR11a, phenyl, C3-C8cycloalkyl, C3-C20heteroaryl, OR4a, SR9a or NR10aR11a, or by one or more C2-C20alkyl which is interrupted by one or more O, S or NR10a, or by one or more phenyl, naphthyl, benzoyl or naphthoyl, each of which is unsubstituted or substituted by OR4a, SR9a or NR10aR11a, or
R10 and R11 independently of each other are C1-C20alkoxy, which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl or C1-C8alkoxyphenyl;
or
R10 and R11 independently of each other are C1-C20alkoxy, which is interrupted by one or more O, S, NR10a, CO, SO or SO2;
or
R10 and R11 independently of each other are C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C4haloalkyl, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, OR4a, SR9a, NR10aR11a, COOR4a, (CO)—R3a or SO2—R3a, or
R10 together with one of the carbon atom of R1 forms a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4-haloalkyl, CN, phenyl, C1-C20alkylphenyl, C1-C8alkoxyphenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a, or
R10 and R11 together with the N-atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or NR10a, and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C20alkyl, OR4a, SR9a, NR10aR11a, (CO)—R3a, NO2, halogen, C1-C4-haloalkyl, CN, phenyl,
or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or NR10a;
R10a and R11a independently of each other are hydrogen, C1-C20alkyl, S(O)m—(C1-C8alkyl), O(CO)(C1-C8alkyl), (CO)(C1-C8alkyl), (CO)O(C1-C8alkyl) or CON(C1-C8alkyl)2;
or
R10a and R11a independently of each other are C1-C20alkyl substituted by one or more halogen, OH, SH, CN, C3-C8alkenoxy, OCH2CH2CN, OCH2CH2 (CO)O(C1-C8alkyl), O(CO)—(C1-C8alkyl), O(CO)—(C2-C4)alkenyl, O(CO)-phenyl, (CO)OH, (CO)O(C1-C8alkyl), C3-C8cycloalkyl, SO2—(C1-C4haloalkyl), O(C1-C4haloalkyl), phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl or C3-C8cycloalkyl which is interrupted by one or more O;
or
R10a and R11a independently of each other are C2-C20alkyl interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2, which is unsubstituted or substituted by C3-C8cycloalkyl, OH, SH, O(CO)(C1-C8alkyl), (CO)O(C1-C8alkyl), (CO)N(C1-C8alkyl)2, C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, wherein C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl or N(C1-C8alkyl)2;
or
R10a and R11a independently of each other are C2-C12alkenyl or C3-C8cycloalkyl, each of which is uninterrupted or interrupted by one or more O, S, CO, N(C1-C8alkyl) or COO(C1-C8alkyl);
or
R10a and R11a independently of each other are C6-C20aryl, C3-C20heteroaryl, C6-C20aroyl or C3-C20heteroarylcarbonyl, each of which is unsubstituted or substituted by one or more halogen, CN, NO2, OH, C1-C8alkyl, C1-C4haloalkyl, C1-C8alkoxy, phenyl-C1-C3alkyloxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2, diphenylamino, (CO)O(C1-C8alkyl), (CO)—C1-C8alkyl or (CO)N(C1-C8alkyl)2, phenyl or benzoyl;
or
R10a and R11a independently of each other are C1-C20alkanoyl, C3-C12alkenoyl, each of which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, OH, C1-C8alkoxy, phenoxy, C1-C8alkylsulfanyl, phenylsulfanyl, N(C1-C8alkyl)2 or diphenylamino;
or
R10a and R11a independently of each other are C1-C20alkoxy, which is unsubstituted or substituted by one or more halogen, phenyl, C1-C8alkylphenyl or C1-C8alkoxyphenyl;
or
R10a and R11a independently of each other are C1-C20alkoxy, which is interrupted by one or more O, S, N(C1-C8alkyl), CO, SO or SO2;
or
R10a and R11a independently of each other are C6-C20aryloxy or C3-C20heteroaryloxy, each of which is unsubstituted or substituted by one or more halogen, C1-C8alkyl, C1-C4haloalkyl, phenyl, C1-C8alkylphenyl, C1-C8alkoxyphenyl, CN, NO2, C1-C8alkoxy, C1-C8alkylsulfanyl, N(C1-C8alkyl)2, CO(OC1-C8alkyl), (CO)—(C1-C8alkyl) or SO2—(C1-C8alkyl);
or
R10a and R11a together with the N-atom to which they are attached form a 5- or 6-membered saturated or unsaturated ring which is uninterrupted or interrupted by O, S or N(C1-C8alkyl), and which 5- or 6-membered saturated or unsaturated ring is unsubstituted or substituted by one or more C1-C8alkyl, C1-C8alkoxy, C1-C8alkylsulfanyl, N(C1-C8alkyl)2, NO2, halogen, C1-C4haloalkyl, CN, phenyl or C3-C20cycloalkyl which is uninterrupted or interrupted by one or more O, S, CO or N(C1-C8alkyl);
R12 and R13 independently of each other are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or
R12 and R13 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
or
R12 and R13 are halogen, CN, OR4, SR9, SOR9, SO2R9 or NR10R11, wherein the substituents OR4, SR9 or NR10R11 optionally form 5- or 6-membered rings via the radicals R4, R9, R10 and/or R11 with one of the carbon atoms of the phenyl, naphthyl, benzoyl or naphthoyl group or that of the substituent R3a;
or
R12 and R13 together are a group wherein R14, R15, R16 and R17 independently of one another are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or R14, R15, R16 and R17 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
or R14, R15, R16 and R17 are halogen, CN, OR4, SR9 or NR10R11;
or
R12 and R13 together are a group
wherein R18 and R19 independently of each other are hydrogen, C1-C12alkyl optionally substituted by one or more halogen, phenyl, CN, —OH, —SH, C1-C4alkoxy, (CO)OH or (CO)O(C1-C4alkyl);
or R18 and R19 are phenyl optionally substituted by one or more C1-C6alkyl, halogen, CN, OR4, SR9 or NR10R11;
m is 1 or 2;
and
Q is CO or a direct bond.

177 more elements

Facts

Application

19/475,893Filed 10 Apr 2024

Priority

EP 23173022.712 May 2023

Published

8 Oct 2026

Term ends

Not estimatedThe source records don’t support an estimate.

Classification5 codes

C09K 19/54
Characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles: additives…
C09K 19/3452
The heterocyclic ring being a six-membered aromatic ring containing two nitrogen atoms: pyrazine
C09K 19/3497
Having sulfur as hetero atom: the heterocyclic ring containing sulfur and nitrogen atoms
C09K 2019/0448
Characterized by a linking chain between rings or ring systems, a bridging chain between extensive mesogenic moieties or an end chain group: the…