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US 2026/0295984 A1Published application
Multilayer packaging film
AssigneeNovamont S.p.A.
InventorsMariangela AIANI, Catia BASTIOLI, Paola COMAZZI, SebastÌà GESTI GARCIA, Tiziana MILIZIA, Roberto PONTI, Claudio RUSSO
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Abstract
The present invention relates to a biodegradable multilayer packaging film comprising at least one layer A and one layer B and having an A/B/A arrangement of said layers. Said multilayer film comprises a biodegradable polyester, a polyhydroxyalkanoate and optionally an antifog agent.
Claims20
A multilayer packaging film comprising at least one layer A and one layer B and having an A/B/A arrangement of said layers where layer A comprises:
- i. 95-100% by weight of the sum of components i.-ii. of a biodegradable aliphatic aromatic polyester with a melt strength of 0.007 N-0.04 N and:
- Mn
- ≥
- 40000
- Mw
- /
- q
- ≤
- 9
-
- 0
-
- 0
-
- 0
-
- 0
- ,
- where Mn and Mw are the number average molecular weight and the weight average molecular weight respectively, and “q” is the percentage by weight of polyester oligomer having a molecular weight by GPC≤10000;
- where the melt strength is measured according to ISO 16790:2005 at 180° C. and γ=103.7s−1 using a capillary of 1 mm diameter and L/D=30 at a constant acceleration of 6 mm/sec2 and a stretching length of 110 mm;
- “Mn” and “Mw” are measured by gel permeation chromatography (GPC);
- and
- ii. 0-5% by weight of the sum of components i.-ii. of an antifog agent selected from the esters of a polyfunctional alcohol preferably from the condensation products of a polyfunctional alcohol with a fatty acid, provided that said ester is not a stearate;
- and where layer B comprises:
- iii. 60-90% by weight, with respect to the sum of components iii.-v., of at least one polyester comprising:
- a. a dicarboxylic component containing with respect to the total dicarboxylic component:
- a1) 30-60% in moles of units derived from at least one aromatic dicarboxylic acid;
- a2) 70-40% in moles of units derived from at least one saturated aliphatic dicarboxylic acid;
- (a3) in moles of units derived from at least one unsaturated aliphatic dicarboxylic acid;
- b. a diol component comprising with respect to the total diol component
- b1) 95-100% in moles of units derived from at least one saturated aliphatic diol;
- b2) 0-5% in moles of units derived from at least one unsaturated aliphatic diol;
- iv. 10-40% by weight, with respect to the sum of components iii.-v., of one or more polyhydroxyalkanoates;
- and
- v. 0-1% by weight, with respect to the sum of the components iii.-v., of at least one cross-linking agent and/or chain extender;
- further characterised in that the content of component iv. in the multilayer film is between 1.6 and 11% by weight with respect to components i.-v.
33 more elements
Dependencies are inferred from the claim text.