Membrane-less system for continuous generation of gases
AssigneeTechnion Research & Development Foundation Limited
InventorsAvner ROTHSCHILD, Ilya SLOBODKIN, Elena DAVYDOVA, Anna BREYTUS
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Abstract
The technology disclosed herein generally concerns a system and a process for continuous generation of hydrogen and oxygen gases.
Claims20
1-58. (canceled)
A redox system for continuous generation of hydrogen gas and oxygen gases, the system comprising a plurality of reactors for cycling a halide-based electrolyte solution comprising a soluble halide redox couple (halide SRC), such that the halide SRC in a reduced state is oxidized in an electrochemical reaction complementing hydrogen gas evolution, without evolution of oxygen gas, and the oxidized halide SRC, in presence of a catalyst, spontaneously evolves oxygen.
A system for continuous generation of oxygen and hydrogen gases, the system comprising an electrode assembly and two or more reactors, wherein
- at least one of said reactors being an electrolytic cell comprising an electrode assembly and configured to oxidize halide electrolyte ions into a corresponding oxidized halide form and to evolve hydrogen gas;
- and
- at least one another of said reactors being a catalytic cell comprising at least one catalyst capable of reverting the oxidized halide form of the electrolytic cell to a reduced form;
- wherein the oxidized halide electrolyte is flown from the electrolytic cell to the catalytic cell and the reduced halide electrolyte is flown from the catalytic cell to the electrolytic cell.
The system according to claim 70, wherein cathode being provided with a semipermeable chromium hydroxide film.
A process for simultaneously generating hydrogen and oxygen gases, the process comprising oxidizing a reduced form of a halide SRC in an electrochemical reaction under conditions complementing a hydrogen evolution reaction (HER), without evolving oxygen gas, and reducing the oxidized form of the halide SRC to spontaneously generate oxygen gas.
A process for simultaneously generating hydrogen and oxygen gases, the process comprising:
- oxidizing a reduced form of a halide SRC being a bromide SRC or a chloride SRC in an electrolytic cell, under conditions complementing hydrogen evolution, without generating oxygen gas,
- separating the hydrogen gas,
- reducing the oxidized form of the halide SRC to spontaneously generate oxygen gas, and
- separating the oxygen gas,
- wherein the halide SRC is provided in an electrolyte solution maintained at a pH between 4 and 10 and at a temperature between 15 and 95°.
Dependencies are inferred from the claim text.