Top plate for cooking device, production method therefor, and method for assessing charring
AssigneeNippon Electric Glass Co., Ltd.
InventorToshiyuki KAJIOKA
Life of this patent
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Abstract
Provided is a cooker top plate that enables, upon occurrence of char sticking to a cooking surface due to such factors as spilling of foods, easy removal of the sticking char and has excellent hardness on the cooking surface side. A cooker top plate 1 includes: a glass substrate 2; and a coating film 3 that is provided on a principal surface of the glass substrate 2 and contains an organo-polysiloxane having a trifunctional siloxane unit represented by formula (1) below, wherein the coating film 3 has a three-dimensional cross-linked structure containing a siloxane bond and has a thickness of not more than 100 nm. in the formula (1), R1 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group or a vinyl group.
Claims21
1:
- A cooker top plate comprising:
- a glass substrate;
- and
- a coating film that is provided on a principal surface of the glass substrate and contains an organo-polysiloxane having a trifunctional siloxane unit represented by formula (1) below,
- wherein the coating film has a three-dimensional cross-linked structure containing a siloxane bond and a thickness of not more than 100 nm.
- in the formula (1), R1 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group or a vinyl group.
2:
- The cooker top plate according to claim 1, wherein a surface of the coating film has an arithmetic mean height Sa of not less than 0.4 nm and not more than 10 nm measured with a size of a measurement view field of 316.77 μm×237.72 μm and a resolution of 640 pixels×480 pixels.
3:
- The cooker top plate according to claim 1, wherein a water contact angle of a surface of the coating film is not less than 80 degrees.
4:
- The cooker top plate according to claim 1, wherein the glass substrate is made of a borosilicate glass or a low-expansion crystallized glass.
5:
- The cooker top plate according to claim 1, wherein the glass substrate has an average coefficient of linear thermal expansion of not more than 40×10−7/° C. at 30° C. to 380° C.
6:
- The cooker top plate according to claim 1, wherein the coating film contains a hydrolytic condensate of a trifunctional alkoxide represented by the following formula (2):
- in the formula (2), R1 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group or a vinyl group and R represents an alkoxy group.
7:
- The cooker top plate according to claim 6, wherein the R1 of a compound represented by the formula (2) is a methyl group.
8:
- The cooker top plate according to claim 1, wherein a pencil hardness of the cooker top plate measured from a side thereof where the coating film is located is not less than 9H.
9:
- The cooker top plate according to claim 1, wherein when a sample for char sticking evaluation is made by dropping an evaluation liquid onto a surface of the coating film and heating the liquid and an image of the sample for char sticking evaluation is taken from a side of the glass substrate opposite to the coating film, an area ratio of a char sticking portion determined from the taken image is not more than 70%.
10:
- The cooker top plate according to claim 1, wherein when the cooker top plate undergoes a heat resistance test under conditions at a temperature of 350° C. for 24 hours, a change in water contact angle of a surface of the coating film between before and after the heat resistance test is less than three degrees.
11:
- The cooker top plate according to claim 1, wherein a surface of the cooker top plate located on a side thereof having the coating film is a cooking surface on which a cooking utensil is to be placed.
12:
- The cooker top plate according to claim 1, wherein
- a printed layer having a pattern is provided on the principal surface of the glass substrate, and
- the coating film is provided to cover the printed layer on the principal surface of the glass substrate.
13:
- The cooker top plate according to claim 12, wherein the pattern is a dotted, grid, striped or ring-shaped pattern.
14:
- A method for producing a cooker top plate comprising a glass substrate and a coating film provided on a principal surface of the glass substrate, the method comprising the steps of:
- applying, to the principal surface of the glass substrate, a coating liquid containing a compound represented by formula (2) below or a hydrolytic condensate in which at least part of the compound is hydrolyzed and condensed;
- and
- firing at a temperature of not lower than 200° C. the glass substrate having the coating liquid applied thereto, thus forming the coating film on the principal surface of the glass substrate.
- in the formula (2), R1 represents an alkyl group having 1 to 6 carbon atoms, a phenyl group or a vinyl group and R represents an alkoxy group.
15:
- The method for producing a cooker top plate according to claim 14, wherein the R1 of the compound represented by the formula (2) is a methyl group.
16:
- A char sticking evaluation method for evaluating removability of sticking char on a plate-shaped material, the method comprising:
- a sample making step of preparing a plate-shaped material having a first principal surface and a second principal surface opposed to each other and making a sample for char sticking evaluation on the first principal surface of the plate-shaped material;
- and
- an evaluation step of evaluating removability of sticking char of the sample for char sticking evaluation from a side of the plate-shaped material where the second principal surface is located.
17:
- The char sticking evaluation method according to claim 16, wherein the evaluation step comprises:
- an imaging step of taking an image of the sample for char sticking evaluation from the side of the plate-shaped material where the second principal surface is located;
- and
- a measurement step of measuring, from the image taken in the imaging step, an area of at least one of a char sticking portion and a char non-sticking portion of the sample for char sticking evaluation.
18-21. (canceled)
22:
- The char sticking evaluation method according to claim 17, wherein in the measurement step a char sticking area ratio is determined as a ratio of the area of the char sticking portion to an area of an entire region where the sample for char sticking evaluation is provided.
23:
- The char sticking evaluation method according to claim 22, wherein in the measurement step whether the plate-shaped material is a non-defective product or a defective product is determined from the char sticking area ratio.
24:
- A cooker top plate having a char sticking area ratio of not more than 70% determined by the char sticking evaluation method according to claim 16.