Process For Preparing Biodegradable Polyester And Biodegradable Polyester Prepared Thereby
AssigneeHanwha Totalenergies Petrochemical Co., Ltd.
InventorsIn Ho KIM, Dohoon LEE, Wankeun KIM
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Abstract
Provided is a process for preparing a biodegradable polyester resin with suppressed discoloration and to a biodegradable polyester resin prepared by the process. The biodegradable polyester resin prepared by the above preparation process can be used for applications such as disposable films or sheets, tableware, and agricultural films or sheets since its discoloration is effectively suppressed.
Claims14
A biodegradable polyester resin, which comprises dicarboxylic acid residues derived from an aliphatic dicarboxylic acid and an aromatic dicarboxylic acid and diol residues derived from an aliphatic diol having a short chain length of less than 4 carbon atoms, and has a melt flow index of 100 g/10 minutes or less when measured at 190° C. under a load of 2.16 kg, wherein the color characteristic L* is 60 or more, and each of a* and b* is 8 or less,
- wherein the biodegradable polyester resin is prepared by a process, which comprises (1) subjecting a reaction mixture comprising (a) a dicarboxylic acid component comprising the aromatic dicarboxylic acid and the aliphatic dicarboxylic acid, (b) a diol component comprising the aliphatic diol having a short chain length of less than 4 carbon atoms, and (c) a discoloration inhibitor to an esterification reaction or a transesterification reaction in the presence of the entire amount of a catalyst, or a part thereof, to obtain a prepolymer;
- and (2) subjecting the prepolymer obtained in step (1) to a polycondensation reaction in the presence of a stabilizer and the remainder of the catalyst, or without an additional catalyst, wherein the discoloration inhibitor comprises a compound represented by Formula 1 in an amount of 1.5 to 3.5% by mole when Y is hydrogen or a methyl group, or in an amount of 1.0 to 2.0% by mole when Y is a hydroxyl group, based on the total number of moles of the dicarboxylic acid component (a):
- in the above formula, n, 1≥1, m, k≥0, and Y is hydrogen, a hydroxyl group, or a methyl group.
Dependencies are inferred from the claim text.