Latex polymer dispersion and the aqueous coating composition prepared from the same
AssigneeSpecialty Operation France
InventorsChunying Liu, Rong Er Lin
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Abstract
The present invention relates to a latex prepared from functional monomers M1 and M2, with improved reaction stability and storage stability. In addition, the present invention further relates to an aqueous coating composition prepared from the same, which has improved freeze thaw stability while maintains wet scrub resistance, particularly substantially free of freeze-thaw additives.
Claims20
A latex polymer dispersion prepared by free radical polymerization from a monomer composition comprising:
- a) an anionic monomer M1 comprising at least one ethylenically unsaturated bond and at least one anion;
- b) an alkoxylated (meth)acrylate monomer M2 represent by formula I)
- wherein R1 is selected from H or methyl;
- R2 is selected from H, C1-C4 alkyl;
- R3 is selected from C1-C4 alkyl, and R2 is different from R3;
- R4 is selected from C6-C20 alkyl, or C6-C20 alkenyl;
- m is a number ranging from 15 to 60;
- n is a number ranging from 0 to 10;
- m+n is a number ranging from 15 to 60;
- and
- c) an ethylenically unsaturated monomer selected from acrylic acid, methacrylic acid, acrylate ester, methacrylate ester, styrene, vinyl acetate, C4-C8 conjugated dienes, vinyl chloride, acrylonitrile, methacrylonitrile, ureido methacrylate, itaconic acid or ester, crotonic acid or ester, maleic acid or ester, fumaric acid or ester, and ethylene, or combinations thereof.
An aqueous coating composition, comprising a latex binder polymer prepared from a monomer composition comprising:
- a) an anionic monomer M1 comprising at least one ethylenically unsaturated bond and at least one anion;
- b) an alkoxylated (meth)acrylate monomer M2 represent by formula I)
- wherein R1 is selected from H or methyl;
- R2 is selected from H, C1-C4 alkyl;
- R3 is selected from C1-C4 alkyl, and R2 is different from R3;
- R4 is selected from C6-C20 alkyl, or C6-C20 alkenyl;
- m is a number ranging from 15 to 60;
- n is a number ranging from 0 to 10;
- m+n is a number ranging from 15 to 60;
- and
- c) an ethylenically unsaturated monomer selected from acrylic acid, methacrylic acid, acrylate ester, methacrylate ester, styrene, vinyl acetate, C4-C8 conjugated dienes, vinyl chloride, acrylonitrile, methacrylonitrile, ureido methacrylate, itaconic acid or ester, crotonic acid or ester, maleic acid or ester, fumaric acid or ester, and ethylene, or combinations thereof.
Dependencies are inferred from the claim text.