US 2026/0258200 A1Published application

Siloxane modified and silane modified polymers via direct insertion of silyl vinyl groups into metal-carbon bonds

OwnerLixin Suninventor

Life of this patent

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Abstract

Processes, and related compositions, to form a siloxane modified olefin-based polymer, a silane modified olefin-based polymer, or a silane, each process, as described herein. Each process forms an Si—C bond through insertion of silyl vinyl into a metal carbon bond. The silyl vinyl double bond directly inserts into the metal-carbon bond to form a new, for example, alkyl-Si linkage.

Claims18

Dependent claims

A process to form a composition comprising a siloxane modified olefin-based polymer, said process comprising reacting A) with B), each as shown below, to form C) as shown below:

A) M[(CR1R2—CR3R4)n-CH3]x where M is a metal selected from Zn or Al;
x is 2 or 3, and if x=2, then M is Zn, and if x=3, then M is Al;
each n is independently ≥1;
and for each respective 11 value, each of R1, R2, R3, R4 is independently H or a hydrocarbyl;
and R1 may or may not be the same for each successive repeat unit;
R2 may or may not be the same for each successive repeat unit;
R3 may or may not be the same for each successive repeat unit;
R4 may or may not be the same for each successive repeat unit;
B) a polysiloxane comprising at least one silyl vinyl group;
C) to form one or more polysiloxane-M-polymer complexes, each independently selected from i, ii, iii, iv, v, vi, vii, viii, ix or x:
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
x=1 or 2, and if x=1, then M is Zn, and if x=2, then M is Al;
and the asterisk (*) represents the remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and R″ is a hydrocarbyl or a heterohydrocarbyl;
x=1 or 2, and if x=1, then M is Zn, and if x=2, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CRlR2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each R″ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CR1R2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CR1R2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
or
x) any combination thereof;
hydrolyzing the one or more polysiloxane-M polymer complexes (C) to form the siloxane modified olefin-based polymer.

46 more elements

Dependencies are inferred from the claim text.

Facts

Application: 19/164,024Filed 28 Jun 2024
Priority: 1 Jul 2023
Published: 3 Sep 2026
Term ends: Not estimatedThe source records don’t support an estimate.

Classification6 codes

C08G 77/20
Polysiloxanes: containing silicon bound to unsaturated aliphatic groups
C08G 77/388
Containing atoms other than carbon, hydrogen, oxygen or silicon: containing nitrogen
C08G 77/442
Block-or graft-polymers containing polysiloxane sequences: containing vinyl polymer sequences
C08L 83/04
Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with…

Family

Application63/511,642Us provisional application · filed 1 Jul 2023
US 2026/0258200 A1This patent

From the US filing history. Foreign family members aren’t listed.

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Abstract

A process to form a composition comprising a siloxane modified olefin-based polymer, said process comprising reacting A) with B), each as shown below, to form C) as shown below:

A) M[(CR1R2—CR3R4)n-CH3]x where M is a metal selected from Zn or Al;
x is 2 or 3, and if x=2, then M is Zn, and if x=3, then M is Al;
each n is independently ≥1;
and for each respective 11 value, each of R1, R2, R3, R4 is independently H or a hydrocarbyl;
and R1 may or may not be the same for each successive repeat unit;
R2 may or may not be the same for each successive repeat unit;
R3 may or may not be the same for each successive repeat unit;
R4 may or may not be the same for each successive repeat unit;
B) a polysiloxane comprising at least one silyl vinyl group;
C) to form one or more polysiloxane-M-polymer complexes, each independently selected from i, ii, iii, iv, v, vi, vii, viii, ix or x:
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
x=1 or 2, and if x=1, then M is Zn, and if x=2, then M is Al;
and the asterisk (*) represents the remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and R″ is a hydrocarbyl or a heterohydrocarbyl;
x=1 or 2, and if x=1, then M is Zn, and if x=2, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CRlR2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each R″ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CR1R2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
x=0 or 1, and if x=0 (the [(CR1R2-CR3R4)n-CH3]) moiety is not present), then M is Zn, and if x=1, then M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R and R′ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
where each n is defined above, and each respective unit of R1, R2, R3, R4 is defined above;
and each of R, R′ and R″ is independently a hydrocarbyl or a heterohydrocarbyl;
and M is Al;
and each asterisk (*) independently represents the respective remainder of the complex;
or
x) any combination thereof;
hydrolyzing the one or more polysiloxane-M polymer complexes (C) to form the siloxane modified olefin-based polymer.

46 more elements

Facts

Application

19/164,024Filed 28 Jun 2024

Priority

1 Jul 2023

Published

3 Sep 2026

Term ends

Not estimatedThe source records don’t support an estimate.

Classification6 codes

C08G 77/20
Polysiloxanes: containing silicon bound to unsaturated aliphatic groups
C08G 77/388
Containing atoms other than carbon, hydrogen, oxygen or silicon: containing nitrogen
C08G 77/442
Block-or graft-polymers containing polysiloxane sequences: containing vinyl polymer sequences
C08L 83/04
Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with…