Organosilicon polymer and use thereof
AssigneeBeijing Mapu New Materials Co., Ltd.
InventorsLingfei JIANG, Xiangjing KONG
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Abstract
An organosilicon polymer and a use thereof are provided. The organosilicon polymer has a repeating unit generated by a silicon-containing monomer I-1 and an optional silicon-containing monomer I-2 and a repeating unit generated by a monomer II. The polymer or a treating agent containing the polymer can be used for treating various articles such as textiles, paper products, and stones, and provides the articles with an oil and water repelling function.
Claims16
An organosilicon polymer comprising a repeating unit derived from a monomer I and a repeating unit derived from a monomer II, the monomer I comprising a silicon monomer I-1 and an optional silicon monomer I-2, wherein
- a) the general structural formula of the silicon monomer I-1 is shown in Formula I-1:
- in Formula I-1, R1 is selected from hydrogen atom or a C1-C20 alkyl group;
- B is a C1-C20 alkylene group;
- X is selected from the group represented by X-1 and the group represented by X-2,
- R2 is selected from hydrogen atom or a C1-C20 alkyl group;
- Z1 is selected from the following group:
- in group Z1, R4 is independently selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, a C7-C12 alkylaryl group, or a R5—O—R6— group, and R5 is selected from a C1-C10 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, or a C7-C12 alkylaryl group, and R6 is a C1-C10 alkylene group, and 1≤a≤200;
- Y1 and Y2 are the same or different and are independently selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, or a C7-C12 alkylaryl group, and the structure of Formula (I), with the condition that when a is 1, Y1 and/or Y2 is the structure of Formula (I), and when a is greater than 1 and ≤200, at least one Y1 is the structure of Formula (I) and/or at least one Y2 is the structure of Formula (I):
- R7 is independently selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, or a C7-C12 alkylaryl group;
- R8 is independently selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, a C7-C12 alkylaryl group, or a R9—O—R10— group, wherein R9 is a C1-C10 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group or a C7-C12 alkylaryl group, and R10 is a C1-C10 alkylene group, and 0≤b≤200;
- the general structural formula of the silicon monomer I-2 is shown in Formula I-2:
- in Formula I-2, R1 is selected from hydrogen atom or a C1-C20 alkyl group;
- B is a C1-C20 alkylene group;
- X is selected from the group represented by X-1 and the group represented by X-2,
- R2 is selected from hydrogen atom or a C1-C20 alkyl group;
- Z2 is selected from the following group:
- in group Z2, R3 is independently selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, or a C7-C12 alkylaryl group, and R4 is selected from a C1-C20 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, a C7-C12 alkylaryl group, or a R5—O—R6— group, and R5 is selected from a C1-C10 alkyl group, a C6-C20 aryl group, a C7-C12 aralkyl group, or a C7-C12 alkylaryl group, and R6 is a C1-C10 alkylene group, and 1≤a≤200;
- b) the general structural formula of the monomer II is shown in Formula II:
- wherein R1 and R2 are independently selected from hydrogen atom or a C1-C20 alkyl group;
- B is a C1-C20 alkylene group;
- R3 and R4 are independently selected from hydrogen atom, a C1-C18 alkyl group, a hydroxyethyl group or a benzyl group, or R3 and R4 are jointed and, together with the nitrogen atom, form a morpholino group, a piperidino group, or a pyrrolidino group.
(canceled)
Dependencies are inferred from the claim text.