Processes for preparing c2 to c4 hydrocarbons using hybrid catalysts

A process for preparing C2 to C4 hydrocarbons comprising:

• introducing a feed stream comprising hydrogen gas and a carbon-containing gas selected from the group consisting of carbon monoxide, carbon dioxide, and mixtures thereof into a reaction zone of a reactor;
• and
• converting the feed stream into a product stream comprising C2 to C4 hydrocarbons in the reaction zone in the presence of a hybrid catalyst, wherein
• the hybrid catalyst comprises:
• a metal oxide catalyst component supported on zirconia, the metal oxide catalyst component comprising gallium oxide and a rare earth oxide;
• and
• a microporous catalyst component comprising a molecular sieve having 8-MR (Member Ring) pore openings.