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US 2026/0249272 A1Published application
Catalyst for decomposing perfluorocompounds
AssigneeEcoprohn
InventorsJIN HONG KIM, MIN JI KIM, SEUNG HWAN JI, HYE IN LEE, HYE JIN AN
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Abstract
A catalyst for perfluorinated compound decomposition includes a first catalyst which includes an aluminum oxide, and a second catalyst which includes at least one oxide selected from the group consisting of Zr, Ce and Ga, wherein a ratio of a weight of the second catalyst to a total weight of the first catalyst is 0.02 to 0.3. The lifespan characteristics and initial activity of the catalyst for perfluorinated compound decomposition may be improved.
Claims15
1:
- A catalyst comprising:
- a first catalyst comprising an aluminum oxide;
- and
- a second catalyst comprising at least one oxide selected from the group consisting of Zr, Ce and Ga,
- wherein a ratio of a weight of the second catalyst to a total weight of the first catalyst is 0.02 to 0.3.
2 more elements
2:
- The catalyst according to claim 1, wherein the aluminum oxide comprises at least one form selected from the group consisting of boehmite (hydrated alumina), alpha alumina (α-alumina), gamma alumina (γ-alumina), delta alumina (δ-alumina) and theta alumina (θ-alumina).
3:
- The catalyst according to claim 1, wherein the second catalyst comprises at least one selected from the group consisting of zirconium oxide (ZrO2), cerium oxide (CeO2) and gallium oxide (Ga2O3).
4:
- The catalyst according to claim 1, wherein the second catalyst comprises at least one selected from the group consisting of zirconium oxide, cerium oxide and gallium oxide, and a mixed phase of alumina and phosphorus.
5:
- The catalyst according to claim 1, further comprising a third catalyst comprising a phosphorus-containing compound.
6:
- The catalyst according to claim 5, wherein a ratio of a converted weight of phosphorus included in the third catalyst to a total weight of the first catalyst is 0.01 to 0.1, and
- the converted weight of phosphorus is a weight obtained by converting the content of phosphorus included in the third catalyst to a content of P2O5.
7:
- The catalyst according to claim 5, wherein the third catalyst further comprises a compound containing at least one selected from the group consisting of B, S, P, Cs, Ca and K.
8:
- The catalyst according to claim 5, further comprising a fourth catalyst comprising at least one oxide selected from the group consisting of Zn, Ni, W, Co, Ni, Cr and Mo.
9:
- The catalyst according to claim 1, wherein a ratio of a crystal structure of the second catalyst, which is measured through X-ray diffraction (XRD) analysis and defined by Equation 1 below, is 0.2 to 0.9:
- Ratio
-
- of
-
- crystal
-
- structures
- =
- A
- /
- B
- [
- Equation
-
- 1
- ]
- wherein Equation 1, A is an XRD peak area corresponding to a monoclinic crystal structure of the second catalyst, and B is an XRD peak area corresponding to a tetragonal crystal structure of the second catalyst.
15 more elements
10:
- The catalyst according to claim 9, wherein a ratio of the weight of the fourth catalyst to the total weight of the first catalyst is 0.01 to 0.2.
11:
- The catalyst according to claim 1, wherein a ratio of the weight of the first catalyst to a total weight of the catalyst is 0.67 to 0.96.
12:
- The catalyst according to claim 1, wherein the catalyst has a honeycomb structure shape comprising a plurality of through channels formed therein.
13:
- The catalyst according to claim 12, wherein the number of through channels per square inch (CPSI) in a planar direction perpendicular to an extension direction of the plurality of through channels is 50 to 150.
14:
- The catalyst according to claim 12, wherein a channel length ratio defined by Equation 2 below is 1 to 5:
- Channel
-
- length
-
- ratio
- =
- L
- /
- T
- [
- Equation
-
- 2
- ]
- wherein Equation 2, L is a length of a major axis of each of the plurality of through channels in the planar direction, and T is the shortest distance between a through channel adjacent to one side of the catalyst and the one side.
13 more elements
15:
- An apparatus for perfluorinated compound decomposition, the apparatus comprising:
- a catalyst layer comprising the catalyst for perfluorinated compound decomposition of claim 12;
- and
- a heat storage body disposed on a lower portion of the catalyst layer.
1 more element