Catalyst, method for producing catalyst, and method for producing acrylonitrile
AssigneeAsahi Kasei Kabushiki Kaisha
InventorsShota MIURA, Shota AIKI
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Abstract
Provided is an ammoxidation reaction catalyst comprising a support and a metal oxide supported on the support, wherein the support comprises silica; the metal oxide is represented by the following formula (1): Mo12-cBiaFebWcCedXeYfZgRbhOi . . . (1) wherein X to Z and a to i are as described in the present specification; an amount of the support is 46.0% by mass or less based on the mass of the ammoxidation reaction catalyst; a value of a+c+d calculated from the atomic ratios described in the formula (1) is 0.21 or more and 1.82 or less; and a value of d/(a+d) calculated from the atomic ratios described in the formula (1) is more than 0.50 and 0.90 or less.
Claims11
1-7. (canceled)
An oxidation reaction catalyst comprising a support and a metal oxide supported on the support, wherein
- the support comprises silica;
- the metal oxide is represented by the following formula (1):
- wherein
- X is one or more elements selected from the group consisting of nickel, cobalt, magnesium, calcium, zinc, strontium, and barium,
- Y is one or more elements selected from the group consisting of chromium, lanthanum, neodymium, yttrium, praseodymium, samarium, aluminum, gallium, and indium,
- Z is one or more elements selected from the group consisting of potassium and cesium,
- a to h satisfy the following relationships:
- 0
- .
- 1
- ≤
- a
- ≤
- 2.
- ,
- 0.1
- ≤
- b
- ≤
- 3.
- ,
- 0.01
- ≤
- c
- ≤
- 1.
- ,
- 0
- <
- d
- ≤
- 3.
- ,
- 0
- ≤
- e
- ≤
- 1
-
- 0
- .0
- ,
- 0
- ≤
- f
- ≤
- 3.
- ,
- 0
- ≤
- g
- ≤
- 2.
- ,
- and
- 0.1
- ≤
- h
- ≤
- 0
- .
- 2
- ,
- and
- i is the number of oxygen atoms necessary for satisfying valence requirements of the other elements present;
- an amount of the support is 46.0% by mass or less based on the mass of the oxidation reaction catalyst;
- a value of a+c+d calculated from the atomic ratios described in the formula (1) is 0.21 or more and 1.82 or less;
- and
- a value of d/(a+d) calculated from the atomic ratios described in the formula (1) is more than 0.50 and 0.90 or less.
Dependencies are inferred from the claim text.