Positive electrode active material for nonaqueous electrolyte secondary battery, and nonaqueous electrolyte secondary battery
AssigneeBASF SE
InventorsZhenji HAN, Jumpei NAKAYAMA, Daisuke MORITA, Masatoshi MATSUMOTO, Kazumichi KOGA, Kazutoshi MATSUMOTO
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Abstract
Disclosed herein are a positive electrode active material, a method of using the positive electrode active material, the method including using the positive electrode active material for inhibiting thermal runaway in a nonaqueous electrolyte secondary battery, and a nonaqueous electrolyte secondary battery employing this positive electrode active material.
Claims17
A method of using a positive electrode active material comprising a composite oxide that contains at least lithium, a transition metal, and oxygen, wherein:
- when a volume-based particle size frequency distribution of primary particles of the composite oxide is separated into a plurality of peaks, these peaks include specific peaks comprising:
- a main peak exhibiting a maximum value of peak area, and at least one peak having an area in a range of from 0.1 to 1, in terms of area ratio, with respect to the area of the main peak, and
- ratios of primary particle size (large particle size/small particle size) at peak tops of adjacent specific peaks are all in a range of from 1.2 to 8;
- the method comprising using the positive electrode active material to inhibit or avoid thermal runaway in a nonaqueous electrolyte secondary battery.
A positive electrode active material for a nonaqueous electrolyte secondary battery, the positive electrode active material comprising a composite oxide that contains at least lithium, a transition metal, and oxygen, wherein:
- when a volume-based particle size frequency distribution of primary particles of the composite oxide is separated into a plurality of peaks, these peaks include specific peaks comprising:
- a main peak exhibiting a maximum value of peak area, and at least one peak having an area in a range of from 0.1 to 1, in terms of area ratio, with respect to the area of the main peak, and
- ratios of primary particle size (large particle size/small particle size) at peak tops of adjacent specific peaks are all in a range of from 1.2 to 8.
Dependencies are inferred from the claim text.