Reinforced polyurethane rigid foam material and preparation method therefor
AssigneeJiangsu Yoke Technology Co., Ltd
InventorsHeng Cao, Qi Shen, Hongfei Zhu, Jinhe Fan, Huabing Wu, Jianqing Ma, Jian Sun
Life of this patent
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Abstract
A reinforced polyurethane rigid foam material and a preparation method therefor are provided. The reinforced polyurethane rigid foam material comprises, in parts by weight: 5-10 parts of glass fiber yarn, 40-60 parts of aromatic polyether polyol, 30-50 parts of aromatic polyester polyol, 30-50 parts of toluene diisocyanate, 40-60 parts of polymethylene polyphenyl polyisocyanate, 5-10 parts of a flame retardant, 5-15 parts of a foaming agent, 1-5 parts of a catalyst and 1-5 parts of a surfactant.
Claims9
A reinforced polyurethane rigid foam material, comprising following raw materials in parts by weight:
- 5-10 parts of glass fiber yarn, 40-60 parts of aromatic polyether polyol, 30-50 parts of aromatic polyester polyol, 30-50 parts of toluene diisocyanate, 40-60 parts of polymethylene polyphenyl polyisocyanate, 5-10 parts of a flame retardant, 5-15 parts of a foaming agent, 1-5 parts of a catalyst, and 1-5 parts of a surfactant,
- wherein the aromatic polyether polyol has a molecular weight of 400-600, a hydroxyl value of 400-600 mg KOH/g, and a viscosity of 5000-9000 mPa·S;
- the aromatic polyester polyol has a molecular weight of 400-600, a hydroxyl value of 300-500 mg KOH/g, and a viscosity of 4000-6000 mPa·S;
- the aromatic polyether polyol is at least one selected from the group consisting of toluene diamine polyether, bisphenol A polyether, and aniline-formaldehyde polyether;
- and the aromatic polyester polyol is at least one selected from the group consisting of phthalic anhydride polyester polyol and trimellitic anhydride polyester polyol;
- the catalyst is a mixture of a small-molecule amine catalyst and an organotin catalyst;
- the small-molecule amine catalyst is any one or a mixture of two selected from the group consisting of triethylenediamine, tetramethylhexanediamine, and triethylamine;
- and the organotin catalyst is any one or a mixture of two selected from the group consisting of stannous octoate and dibutyltin diacetate;
- the flame retardant is any one or a mixture of two selected from the group consisting of tris(2-chloroethyl)phosphate, tris(2-chloropropyl)phosphate, and tris(dichloropropyl)phosphate, and the foaming agent is any one or a mixture of two selected from the group consisting of pentafluoropropane and trans-1-chloro-3,3,3-trifluoropropylene;
- and
- the surfactant is a polysiloxane polymer with a viscosity of 200-600 mPa's and a moisture content of less than 0.05%, and the surfactant is any one or a mixture of two selected from the group consisting of polysiloxane-ethylene oxide AB type linear block copolymer and polysiloxane-propylene oxide ABA type linear block copolymer.
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Dependencies are inferred from the claim text.