Biodegradable perfume composition
AssigneeGivaudan SA
InventorsNicolas ANORGA, Aurelie FERRY, Maxence MOUTTE, Anne-Sylvie SELEZNEFF
Life of this patent
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Abstract
The present invention relates to biodegradable perfume compositions, consumer products containing the compositions, methods of preparing the foregoing, and to methods of enhancing the performance and olfactive diversity of biodegradable perfume compositions.
Claims18
A biodegradable perfume composition, comprising
- a) Group A ingredients selected from the group consisting of at least two biodegradable ingredients selected from 3,8,8,11a-tetramethyldodecahydro-1H-3,5a-epoxynaphtho[2,1-c]oxepine;
- 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol;
- (E)-3,3-dimethyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol;
- (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol;
- (1S,2R,5S,7R,8R)-2,6,6,8-tetramethyltricyclo[5.3.1.01,5]undecan-8-ol;
- 4-methoxy-2,2,7,7-tetramethyltricyclo[6.2.1.01,6]undec-5-ene;
- 1′,1′,5′,5′-Tetramethylhexahydro-spiro[1,3-dioxolane-2,8′(5′H)-2H-2,4a-methanonaphthalene];
- (E)-4-methyldec-3-en-5-ol;
- 1-phenylethyl acetate;
- (2-methoxyethyl)benzene;
- (Z)-hex-3-enyl acetate;
- (Z)-hex-3-en-1-yl butanoate;
- 4-(4-methylpent-3-en-1-yl)cyclohex-3-enecarbaldehyde;
- (4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate;
- dec-9-en-1-ol;
- (4E)-4,8-dimethyldeca-4,9-dienal;
- (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one;
- (E)-1-(2,6,6-trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1-one;
- 5-methyl-5-phenylhexan-3-one;
- 1-methyl-4-(4-methylpentyl)cyclohex-3-enecarbaldehyde;
- 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-enecarbaldehyde;
- 7-hydroxy-3,7-dimethyloctanal;
- 3-(4-(2-methylpropyl)-2-methylphenyl)propanal;
- (E)-methyl non-2-enoate;
- 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one;
- 2-cyclohexylhepta-1,6-dien-3-one;
- (Z)-3-methylcyclotetradec-5-enone;
- 2-ethoxy-4-methylphenol;
- 1-(cyclopropylmethyl)-4-methoxybenzene;
- 2-methyl-4-oxo-4H-pyran-3-yl 2-methylpropanoate;
- 2,4,7-Trimethyl-6-octen-1-ol;
- (2-benzyl-1,3-dioxolan-4-yl)methanol;
- (2-(1-propoxyethoxy)ethyl)benzene;
- 3-phenylbutanal;
- (Z)-3,7,11-trimethyldodeca-6,10-dienal;
- 7-methyl-3-methylideneoct-6-enal;
- hexanal;
- (E)-hex-2-enal;
- 3-(4-propan-2-ylcyclohexen-1-yl)propanal;
- 4-methyl-2-(2-methylprop-1-en-1-yl)tetrahydro-2H-pyran;
- 1,7-dioxacycloheptadecan-8-one;
- (Z)-oxacycloheptadec-10-en-2-one;
- 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran;
- 4-(2-methoxypropan-2-yl)-1-methylcyclohexene;
- (1S,2S,4S)-2-methoxy-1,7,7-trimethylbicyclo[2.2.1]heptane;
- 4,7-dimethyloct-6-en-3-one;
- 6,8-dimethylnonan-2-ol;
- (1S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 2-methylpropanoate;
- 2-cyclohexylhepta-1,6-dien-3-one;
- 2-methyl-4-oxo-4H-pyran-3-yl 2-methylpropanoate;
- ethyl (Z)-2-acetyl-4-methyltridec-2-enoate;
- Akigalawood, or mixtures thereof, and
- b) Optionally Group B ingredients selected from the group consisting of (2-benzyl-1,3-dioxolan-4-yl)methanol;
- (2-(1-propoxyethoxy)ethyl)benzene;
- decanal;
- 2-methyldecanal;
- undec-10-enal;
- undecanal;
- dodecanal;
- 2-methylundecanal;
- heptanal;
- octanal;
- 3,5,5-trimethylhexanal;
- nonanal;
- (E)-non-2-enal;
- prop-2-enyl 2-(3-methylbutoxy)acetate;
- 3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro-1H-benzo[e][1]benzofuran;
- pentyl 2-hydroxybenzoate;
- phenylethyl 2-methylbutanoate;
- (2-(isopentyloxy)ethyl)benzene;
- (4Z)-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undec-4-ene;
- (1S,8aR)-1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulene;
- ((1S,8aR)-1,4,4-trimethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulen-6-yl)methanol;
- (Z)-hex-3-en-1-yl 2-hydroxybenzoate;
- 3-(4-isopropylphenyl)-2-methylpropanal;
- cyclohexyl 2-hydroxybenzoate;
- 6-pentyltetrahydro-2H-pyran-2-one;
- 5-hexyloxolan-2-one;
- 3,7-dimethylocta-1,6-diene;
- 2-methyl-1-phenylpropan-2-ol;
- 2-methyl-1-phenylpropan-2-yl acetate;
- 2-methyl-4-phenylbutan-2-yl acetate;
- 2-methyl-1-phenylpropan-2-ol;
- 2-methyl-1-phenylpropan-2-yl acetate;
- 6-heptyltetrahydro-2H-pyran-2-one;
- 5-octyloxolan-2-one;
- 3-O-[1-(3,3-dimethylcyclohexyl)ethyl]1-O-ethyl propanedioate;
- 1,4-dioxacycloheptadecane-5,17-dione;
- cyclopentadecanone;
- (3E)-oxacyclohexadec-3-en-2-one;
- (E)-oxacyclohexadec-12-en-2-one;
- methyl 3-oxo-2-pentylcyclopentaneacetate;
- 6-ethyloxan-2-one;
- 5-propyloxolan-2-one;
- 1-oxacycloheptadecan-2-one;
- hexyl acetate;
- 5-ethyloxolan-2-one;
- hexyl 2-hydroxybenzoate;
- (E)-4-(2,6,6-trimethyl-1-cyclohex-2-enyl)but-3-en-2-one;
- (E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one;
- (E)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one;
- (E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one;
- cyclohexadecanone;
- (E)-3-methyl-4-(2,6,6-trimethyl-cyclohex-2-en-1-yl)but-3-en-2-one;
- (Z)-6-(pent-2-en-1-yl)tetrahydro-2H-pyran-2-one;
- (Z)-5-(hex-3-en-1-yl)-5-methyloxolan-2-one;
- (E)-6-(pent-3-en-1-yl)-tetrahydro-2H-pyran-2-one;
- (4Z)-hept-4-en-2-yl 2-hydroxybenzoate;
- 3-methyl-5-phenylpentanal;
- 3-methyl-5-phenylpentan-1-ol;
- 5-hexyl-5-methyloxolan-2-one;
- 3-methylcyclopentadecanone;
- 2-(2-(4-methylcyclohex-3-en-1-yl)propyl)-cyclopentan-1-one;
- 5-pentyloxolan-2-one;
- 6-propyltetrahydro-2H-pyran-2-one;
- 5-butyloxolan-2-one;
- 1,1-dimethoxycyclododecane;
- 5-heptyldihydrofuran-2(3H)-one;
- 2-methyl-5-propan-2-ylcyclohexa-1,3-diene;
- 2-phenylethanol;
- 2-phenylethyl acetate;
- 2-phenylethyl butanoate;
- 2-phenylethyl 3-phenylprop-2-enoate;
- 2-phenylethyl formate;
- 2-phenylethyl 2-methylpropanoate;
- 2-phenylethyl 3-methylbutanoate;
- 2-phenylethyl acetate;
- 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal;
- 4-(4-hydroxyphenyl)butan-2-one;
- (1-oxopropoxy)-acetic acid, 1-(3,3-dimethyl cyclohexyl)ethyl ester;
- 6,6-dimethylspiro[bicyclo[3.1.1]heptane-2,2′-oxirane];
- 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol;
- oxacyclohexadecan-2-one;
- 5-methyloxolan-2-one;
- 2-(2-hydroxypropan-2-yl)-5-methylcyclohexanol;
- Patchouli oil;
- Clove oil;
- Geranium oil;
- Orange terpenes;
- Eucalyptus oil;
- Badiane oil;
- Lavandin oil;
- Mint oil;
- Nutmeg oil;
- or mixtures thereof;
- and which is free or substantially free of any of the following non-biodegradable ingredient, referred to as Group C ingredients:
- i. Ingredients comprising a fully or partially hydrogenated methano-indene moiety;
- ii. Ingredients comprising two or more fused-ring moieties selected from 6-butan-2-yl-quinoline;
- 5-isopropylquinoline;
- decahydro-2,2,6,6,7,8,8-heptamethyl indenofuran;
- 1,3,4,5,6,7-hexahydro-1,1,5,5-pentamethyl-2H-2,4a-methanonaphthalene-8-ethanol;
- (4aR,5R,7aS,9R)-octahydro-2,2,5,8,8,9a-hexamethyl-4H-4a,9-methanoazuleno[5,6-d]-1,3-dioxole;
- 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde;
- 7-isopentyl-2H-benzo[b][1,4]dioxepin-3(4H)-one;
- (1R,2S,4R)-2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane];
- 8-methyl-1,5-benzodioxepin-3-one;
- 1,1,2,3,3-pentamethyl-2,3,6,7-tetrahydro-1H-inden-4(5H)-one;
- 1-(6-tert-butyl-1,1-dimethyl-2,3-dihydroinden-4-yl)ethanone;
- 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone;
- 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta-[g]isochromene;
- 1-(1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-naphthalen-2-yl)ethanone;
- 4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine;
- 1-(2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydro-naphthalen-2-yl)ethanone;
- 2,2,7,7-tetramethyltricyclo[-6.2.1.01,6]undecan-5-one;
- 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine;
- 1-((1S,8aS)-1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulen-7-yl)ethanone;
- 1a,3,3,4,6,6-hexamethyl-1a,2,3,4,5,6,7,7a-octahydronaphtho[2,3-b]oxirene;
- 1-(3-methyl-benzofuran-2-yl)ethanone;
- 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane;
- 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate;
- (8aR)-4,4,8,8-tetramethylhexahydro-1H-3,8a-methanonaphthalen-5(6H)-one;
- (4aS,8aR)-7-methyloctahydro-1,4-methanonaphthalen-6(2H)-one;
- 6-(sec-butyl)quinoline;
- (2R,8aS)-3′,6-dimethyl-3,4,4a,5,8,8a-hexahydro-1H-spiro[1,4-methanonaphthalene-2,2′-oxirane];
- and 3,7-dimethyloctan-3-ol;
- and 3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene;
- iii. Ingredients comprising a cyclohexylidene benzoacetonitrile moiety;
- iv. Ingredients comprising an aromatic ring substituted by an aldehyde moiety having a secondary carbon atom in alpha position of the aldehyde group;
- v. Ingredients comprising one or more bridged cycles selected from bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde;
- 3-((1R,2S,4R,6R)-5,5,6-trimethylbicyclo[2.2.1]heptan-2-yl)-cyclohexanol;
- alpha-cedrene epoxide;
- methyl-4(or 1)-isopropyl-1(or 4)-methylbicyclo[2.2.2]oct-5-ene-2-carboxylate;
- 1-methyl-4-(2,2,3-trimethylcyclopentyl)-2-oxabicyclo[2.2.2]octane;
- 6-ethylidenebicyclo-[2.2.1]hept-2-yl propan-2-yl ether;
- and (2S)-ethyl isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate;
- vi. Ingredients comprising a sterically hindered conjugated carbonyl moiety;
- vii. Ingredients comprising a ketal or an acetal moiety selected from 6,6-dimethoxy-2,5,5-trimethylhex-2-ene;
- (1,1-diethoxypropan-2-yl)benzene;
- 2-butyl-4,4,6-trimethyl-1,3-dioxane;
- 2,4,6-trimethyl-4-phenyl-1,3-dioxane;
- (ethoxymethoxy)cyclododecane;
- ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate;
- (2-(1-ethoxyethoxy)ethyl)-benzene;
- (2,2-dimethoxyethyl)benzene;
- 2-(cyclohexylmethyl)-4,4,6-trimethyl-1,3-dioxane;
- or
- viii. An ingredient selected from N-ethyl-N-(m-tolyl)propionamide;
- 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol;
- 3,5-diethyl-2,5-dimethylcyclohex-2-enone;
- (2-methyl-5-prop-1-en-2-ylcyclohexyl) acetate;
- 2-benzyl-2-methylbut-3-enenitrile;
- 2-(tert-pentyl)cyclohexyl acetate;
- ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1-carboxylate;
- allyl 2-(cyclohexyloxy)acetate;
- methyl 1,4-dimethylcyclohexanecarboxylate;
- 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile;
- 2-(tert-butyl)cyclohexyl ethyl carbonate;
- ethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate;
- N,2-dimethyl-N-phenylbutanamide;
- ethyl 2-ethyl-6,6-dimethyl-cyclohex-2-enecarboxylate;
- 2-butyl-4,6-dimethyl-3,6-dihydro-2H-pyran;
- [2-[1-(3,3-dimethylcyclohexyl)ethoxy]-2-methylpropyl]propanoate;
- (1-ethynylcyclohexyl) acetate;
- 3,7-dimethyloctanenitrile;
- (1S,2S,4S)-2-methoxy-1,7,7-trimethyl-bicyclo[2.2.1]heptane;
- 2,4,6-trimethylcyclohex-3-ene-carbaldehyde;
- 2-methyl-3-(4-methylphenyl)propanal;
- (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)-cyclopropyl)-methanol;
- 4-(1-ethoxyethenyl)-3,3,5,5-tetramethylcyclohexan-1-one;
- 2,2-dimethyl-4-phenylpentanenitrile;
- (Z)-3,4,5,6,6-pentamethylhept-3-en-2-one;
- 3,4,5,6,6-pentamethylheptan-2-ol;
- (3E,6E)-2,4,4,7-tetramethylnona-6,8-dien-3-one oxime;
- 2,2,6-trimethyl-6-vinyltetrahydro-2H-pyran;
- 3-methyl-4-(2,2,6-trimethylcyclohexyl)butan-2-ol;
- 2,2-dimethyl-3-(m-tolyl)propan-1-ol;
- 4-[(3E)-4,8-dimethylnona-3,7-dienyl]pyridine;
- 1-(3,5,6-trimethyl-1-cyclohex-3-enyl)ethanone;
- 2-methoxy-1,1′-biphenyl;
- 3-cyclohexyl-2,2-dimethylpropan-1-ol;
- 1-(4-propan-2-ylcyclohexyl)ethanol;
- 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]-deca-3,6-diene;
- 4-(tert-pentyl)cyclo-hexanone;
- methoxycyclododecane;
- 2-ethyl-N-methyl-N-(m-tolyl)butanamide;
- 2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran;
- Ethyl-2,3,6-trimethylcyclohexyl carbonate;
- 2,4-dimethyl-4-phenyl-tetrahydrofuran;
- 2,2,2-trichloro-1-phenylethyl acetate;
- 1-(3,3-dimethylcyclohexyl)ethyl acetate;
- 3-(2-methylpropyl)-1-methylcyclohexanol;
- 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate;
- (E)-5-methylheptan-3-one oxime;
- (4E)-4-[(2Z)-But-2-en-1-ylidene]-3,5,5-trimethylcyclohex-2-en-1-one (mixture of isomers);
- ethyl (1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate;
- 1-((2E,5Z,9Z)-2,7,8-trimethylcyclododeca-2,5,9-trien-1-yl)ethanone;
- 4a,5-dimethyl-3-prop-1-en-2-yl-2,3,4,5,6,7-hexahydro-1H-naphthalene;
- 2,2,5-trimethyl-5-pentylcyclopentanone;
- 4-methyl-4-phenylpentan-2-yl acetate;
- and (2R,5R,8S)-4,4,8-trimethyltricyclo[6.3.1.02,5]dodecan-1-yl acetate.
A method for obtaining a biodegradable perfume composition, the method comprising the step of mixing:
- a) From 8 wt.-% to 40 wt.-% of Group A ingredients;
- b) From 0 wt.-% to 92 wt.-% of Group B ingredients;
- and
- c) From 0 wt.-% to 92 wt.-% of one or more ingredients that are different from Group A and Group B ingredients to complete to 100%.
A method of enhancing the olfactive performance of a biodegradable perfume composition, the method comprising adding at least two Group A ingredients and one or more Group B ingredients to the biodegradable perfume composition.
Dependencies are inferred from the claim text.