US 2026/0226296 A1Published application

Aralkyl resole polymer

OwnerPaul Jonesinventor

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Abstract

The present invention relates to an AB co-polymer or AB co-oligomer having a resole like structure. In particular the invention is directed to an AB co-polymer or AB co-oligomer, a method of preparing the AB co-polymer or AB co-oligomer, a composition comprising the AB co-polymer or AB co-oligomer, and uses thereof. In one aspect, the AB co-polymer or AB co-oligomer is derived from repeating units of A and B, wherein repeating unit A is independently selected from the following structures: and wherein repeating unit B is independently selected from the following structures:

Claims20

Dependent claims

An AB co-polymer or AB co-oligomer derived from repeating units of A and B, wherein each repeating unit A is independently selected from the following structures:

wherein repeating unit B is independently selected from the following structures:
wherein:
represents the point of connection to the adjacent repeating unit or to a terminal group, wherein the terminal group of repeating unit A is —H, and the terminal group of repeating unit B is —R5;
each R is independently selected from:
—CHR4—OH, —CHR4—O—C1 to C20 alkyl, —CHR4—O—C1 to C20 haloalkyl, —CHR4—O—C2 to C20 alkenyl, —CHR4—O—C2 to C20 alkynyl, —CHR4—O—C3 to C20 cycloalkyl, —CHR4—O—C4 to C20 heterocycloalkyl, —CHR4—O—C2 to C20 alkyloxy, —CHR4—O—C6 to C10 aryl, —CHR4—O—C3 to C10 heteroaryl, —CHR4—O—(C1 to C10 alkyl)-(C6 to C10 aryl), —CHR4—O—(C1 to C10 alkenyl)-(C6 to C10 aryl), —CHR4—O—(C1 to C10 alkyl)-(C3 to C10 heteroaryl), —CHR4—O—CHR4-A, and —CHR4—O—B;
wherein the C6 to C10 aryl and the C3 to C10 heteroaryl is optionally substituted;
each R1 is independently selected from:
—C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C1 to C20 alkyloxy, —OR3, —NR32, —SR3, —CN, —NO2, —F, —Cl, —Br, and —I;
each R2 is independently selected from:
—C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C1 to C20 alkyloxy, —OR3, —NR32, —SR3, —CN, —NO2, —F, —Cl, —Br, and —I;
each R3 is independently selected from:
—H, —C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, and —C1 to C20 alkyloxy;
each R4 is independently selected from:
—H, —C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C3 to C20 heterocycloalkyl, an optionally substituted —C6 to C10 aryl, and an optionally substituted —C2 to C10 heteroaryl;
each R5 is independently a suitable leaving group;
each x is independently selected from:
0, 1, and 2, with the proviso that at least one x value within the AB co-polymer or AB co-oligomer is 1 or 2;
each y is independently selected from:
0, 1, 2, and 3;
each z is independently selected from:
0, 1, 2, 3, and 4;
and
wherein the AB co-polymer or AB co-oligomer comprises at least two A repeating units and at least one B repeating unit, and wherein the AB co-polymer or AB co-oligomer comprises no more than 45 A repeating units and B repeating units in total.

20 more elements

Dependencies are inferred from the claim text.

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Abstract

An AB co-polymer or AB co-oligomer derived from repeating units of A and B, wherein each repeating unit A is independently selected from the following structures:

wherein repeating unit B is independently selected from the following structures:
wherein:
represents the point of connection to the adjacent repeating unit or to a terminal group, wherein the terminal group of repeating unit A is —H, and the terminal group of repeating unit B is —R5;
each R is independently selected from:
—CHR4—OH, —CHR4—O—C1 to C20 alkyl, —CHR4—O—C1 to C20 haloalkyl, —CHR4—O—C2 to C20 alkenyl, —CHR4—O—C2 to C20 alkynyl, —CHR4—O—C3 to C20 cycloalkyl, —CHR4—O—C4 to C20 heterocycloalkyl, —CHR4—O—C2 to C20 alkyloxy, —CHR4—O—C6 to C10 aryl, —CHR4—O—C3 to C10 heteroaryl, —CHR4—O—(C1 to C10 alkyl)-(C6 to C10 aryl), —CHR4—O—(C1 to C10 alkenyl)-(C6 to C10 aryl), —CHR4—O—(C1 to C10 alkyl)-(C3 to C10 heteroaryl), —CHR4—O—CHR4-A, and —CHR4—O—B;
wherein the C6 to C10 aryl and the C3 to C10 heteroaryl is optionally substituted;
each R1 is independently selected from:
—C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C1 to C20 alkyloxy, —OR3, —NR32, —SR3, —CN, —NO2, —F, —Cl, —Br, and —I;
each R2 is independently selected from:
—C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C1 to C20 alkyloxy, —OR3, —NR32, —SR3, —CN, —NO2, —F, —Cl, —Br, and —I;
each R3 is independently selected from:
—H, —C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, and —C1 to C20 alkyloxy;
each R4 is independently selected from:
—H, —C1 to C20 alkyl, —C2 to C20 alkenyl, —C2 to C20 alkynyl, —C3 to C20 cycloalkyl, —C3 to C20 heterocycloalkyl, an optionally substituted —C6 to C10 aryl, and an optionally substituted —C2 to C10 heteroaryl;
each R5 is independently a suitable leaving group;
each x is independently selected from:
0, 1, and 2, with the proviso that at least one x value within the AB co-polymer or AB co-oligomer is 1 or 2;
each y is independently selected from:
0, 1, 2, and 3;
each z is independently selected from:
0, 1, 2, 3, and 4;
and
wherein the AB co-polymer or AB co-oligomer comprises at least two A repeating units and at least one B repeating unit, and wherein the AB co-polymer or AB co-oligomer comprises no more than 45 A repeating units and B repeating units in total.

20 more elements