Substituted pyrrolidone compound, preparation method therefor, composition and application thereof

A substituted pyrrolidone compound is as shown in the general formula I.

• wherein, Q represents
• that is unsubstituted or substituted by at least one R11;
• X and Y each independently represent hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, heterocyclyl, heterocyclylalkyl, hydroxyl, hydroxylalkyl, mercapto, mercaptoalkyl, nitro, cyanoalkyl, formyl, trialkylsilyl, —N(R21)2, —OR22, —SR22, —(CO)R22, —(CO)OR22, —(SO2)R22, —(SO)R22, —(SO2)N(R21)2, -alkylene-N(R21)2, -alkylene-OR22, -alkylene-SR22, -alkylene-(CO)R22, -alkylene-(CO)OR22, -alkylene-(SO2)R22, or -alkylene-(SO2)N(R21)2;
• Z represents alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, cycloalkyl, cycloalkylalkyl, aryl, arylalkyl, heterocyclyl, heterocyclylalkyl, hydroxyl, hydroxylalkyl, mercapto, mercaptoalkyl, nitro, cyanoalkyl, formyl, trialkylsilyl, —N(R21)2, —OR22, —SR22, —(SO)R22, —(CO)R22, —(CO)OR22, —(SO2)R22, —(SO2)N(R21)2, -alkylene-N(R21)2, -alkylene-OR22, -alkylene-SR22, -alkylene-(CO)R22, -alkylene-(CO)OR22, -alkylene-(SO2)R22, or -alkylene-(SO2)N(R21)2;
• W1 and W2 each independently represent O or S;
• R6 represents hydrogen, hydroxyl, halogen, alkyl, cycloalkyl, alkoxy, or haloalkyl;
• R7 represents hydrogen, halogen, nitro, cyano, formyl, carboxyl, hydroxyl, hydroxylalkyl, mercapto, mercaptoalkyl, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, —OR22, —SR22, —(SO)R22, —(SO2)R22, —CR23═N—O—R22, -alkylene-OR22, -alkylene-SR22, -alkylene-(SO2)R22, cycloalkyl, cycloalkenyl, aryl, heterocyclyl, —(CO)R22, —(CO)N(R21)2, —(CO)OR22, —N(R21)2, -alkylene-(CO)R22, -alkylene-(CO)N(R21)2, -alkylene-(CO)OR22, or -alkylene-N(R21)2;
• R8 represents hydrogen, alkyl, alkenyl, alkynyl, haloalkyl, haloalkenyl, haloalkynyl, cycloalkyl, or cycloalkylalkyl;
• R1, R2, R3, R4 and R5 each independently represent hydrogen, halogen, nitro, cyano, cyanothio, hydroxyl, mercapto, carboxyl, sulfo, formyl, haloformyl, azido, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, —N(R21)2, —(CO)N(R21)2, —O(CO)N(R21)2, —O(CS)N(R21)2, —(SO2)N(R21)2, —O(SO2)N(R21)2, —PO(OR22)2, —OR22, —(CO)R22, —SR22, —(SO)R22, —(SO2)R22, —Si(R22)3, —O(CO)R22, —O—(SO2)R22, —S(CO)R22, —(SO2)OR22, —O(CO)OR22, —(CO)(CO)OR22, —(CO)OR22, —O—N═C(R23)2, —CR23═N—OH, or —CR23═N—O—R22;
• wherein, the “alkyl”, “alkenyl” or “alkynyl” is optionally substituted by at least one group selected from halogen, nitro, cyano, hydroxyl, mercapto, carboxyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, —N(R21)2, —(CO)N(R21)2, —O(CO)N(R21)2, —O(CS)N(R21)2, —(SO2)N(R21)2, —O(SO2)N(R21)2, —OR22, —(CO)R22, —SR22, —(SO)R22, —(SO2)R22, —O(CO)H, —O(CO)R22, —O—(SO2)R22, —(CO)OR22, —O(CO)OR22, —Si(R22)3, —O(CO)(CO)OH, —O(CO)(CO)OR22, —O— alkylene-(CO)OH, and —O-alkylene-(CO)OR22;
• R11 each independently represents halogen, nitro, cyano, cyanothio, hydroxyl, mercapto, carboxyl, sulfo, formyl, haloformyl, azido, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, —N(R21)2, —(CO)N(R21)2, —O(CO)N(R21)2, —O(CS)N(R21)2, —(SO2)N(R21)2, —O(SO2)N(R21)2, —PO(OR22)2, —OR22, —(CO)R22, —SR22, —(SO)R22, —(SO2)R22, —Si(R22)3, —O(CO)R22, —O—(SO2)R22, —S(CO)R22, —(SO2)OR22, —O(CO)OR22, —(CO)(CO)OR22, —(CO)OR22, —O—N═C(R23)2, —CR23═N—OH, or —CR23═N—O—R22;
• wherein, the “alkyl”, “alkenyl” or “alkynyl” is optionally substituted by at least one group selected from halogen, nitro, cyano, hydroxyl, mercapto, carboxyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, —N(R21)2, —(CO)N(R21)2, —O(CO)N(R21)2, —O(CS)N(R21)2, —(SO2)N(R21)2, —O(SO2)N(R21)2, —OR22, —(CO)R22, —SR22, —(SO)R22, —(SO2)R22, —O(CO)H, —O(CO)R22, —O—(SO2)R22, —(CO)OR22, —O(CO)OR22, —Si(R22)3, —O(CO)(CO)OH, —O(CO)(CO)OR22, —O-alkylene-(CO)OH, and —O— alkylene-(CO)OR22;
• R21 each independently represents hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl, heterocyclyl, —OR22, —(CO)R22, —(CO)OR22, -alkylene-(CO)OR22, —(SO2)R22, —(SO2)OR22, -alkylene-(SO2)R22, —(CO)N(R24)2, or —(SO2)N(R24)2;
• R22 each independently represents alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkenyl, aryl, or heterocyclyl, wherein, the “alkyl”, “alkenyl” or “alkynyl” is optionally substituted by at least one group selected from halogen, cyano, trialkylsilyl, cycloalkyl, cycloalkenyl, aryl, heterocyclyl, —OR25, —SR25, —O(CO)R25, —(CO)R25, —(CO)OR25, and —O(CO)OR25;
• R23 each independently represents hydrogen, halogen, alkoxy, alkoxyalkyl, alkyl, alkenyl, alkynyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, cycloalkenylalkyl, aryl, arylalkyl, heterocyclyl, or heterocyclylalkyl;
• R24 each independently represents hydrogen, alkyl, alkenyl, alkynyl, alkoxy, alkylsulfonyl, cycloalkyl, cycloalkylalkyl, cycloalkenyl, or cycloalkenylalkyl;
• or N(R21)2 and N(R24)2 each independently represent heterocyclyl with a nitrogen atom at 1-position;
• R25 each independently represents hydrogen, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl, phenyl or phenyl that is substituted by at least one group selected from the following:
• halogen, cyano, nitro, alkyl, haloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, alkylsulfonyl, phenoxy and phenoxy that is substituted by at least one group selected from halogen, cyano, nitro, alkyl, haloalkyl, alkoxy and haloalkoxy;
• the foregoing “cycloalkyl”, “cycloalkenyl”, “heterocyclyl” or “aryl” is optionally substituted by at least one group selected from oxo, halogen, cyano, nitro, alkyl, alkenyl, alkynyl, cycloalkyl, haloalkyl, haloalkenyl, haloalkynyl, halocycloalkyl, alkyl-substituted cycloalkyl, —OR10, —SR10, —(CO)OR10, —(SO2)R10, —N(R10)2 and —O-alkylene-(CO)OR10, or two adjacent carbon atoms form a fused ring with —OCH2CH2— or —OCH2O— that is unsubstituted or substituted by halogen;
• R10 each independently represents hydrogen, alkyl, haloalkyl, phenyl, or phenyl that is substituted by at least one group selected from halogen, cyano, nitro, alkyl, haloalkyl, alkoxycarbonyl, alkylthio, alkylsulfonyl, alkoxy, and haloalkoxy.