Low temperature stabilization of liquid oils
AssigneeTopsoe A/S
InventorsChristian Ejersbo STREBEL, David Norman MCCARTHY, Magnus Zingler STUMMANN, Lived Yegres LEMUS-OLSEN
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Abstract
The invention relates to a process and plant for hydrotreating a liquid oil stream such as pyrolysis oil stream by, in continuous operation in a fixed bed reactor, reacting the liquid oil stream with hydrogen in the presence of a reduced nickel (Ni) catalyst at a temperature of 80-250° C., a pressure of 10-200 barg, a liquid hourly space velocity (LHSV) of 0.1-6.0 h−1, and a hydrogen to liquid oil ratio, defined as the volume ratio of hydrogen to the flow of the liquid oil stream, of 100-8000 NL/L, thereby forming a stabilized liquid oil stream.
Claims15
A process for hydrotreating a liquid oil stream by, in a continuous operation in a fixed bed reactor, reacting the liquid oil stream with hydrogen in the presence of a reduced nickel (Ni) catalyst at a temperature of 80-250° C., a pressure of 10-200 barg, a liquid hourly space velocity (LHSV) of 0.1-6.0 h−1, and a hydrogen to liquid oil ratio, defined as the volume ratio of hydrogen to the flow of the liquid oil stream, of 100-8000 NL/L, thereby forming a stabilized liquid oil stream;
- wherein the reduced Ni catalyst is a supported catalyst having a Ni content of 2-30 wt %, based on the total weight of the catalyst;
- wherein the support is selected from any of:
- alumina (Al2O3), alumina magnesium spinel (MgAl2O4), and combinations thereof;
- optionally in combination with a molecular sieve having topology MFI, BEA or FAU;
- and
- wherein said alumina is any of:
- alumina comprising 90-100 wt % gamma alumina;
- as well as having:
- a BET surface area of 230-250 m2/g, a total pore volume (PV) of 800-900 mL/kg as measured by mercury intrusion porosimetry;
- alumina comprising 90-100 wt % gamma alumina;
- as well as having:
- a BET surface area of 165-185 m2/g, a total pore volume (PV) of 950-1100 mL/kg as measured by mercury intrusion porosimetry;
- alumina comprising 80-100 wt % theta alumina and 0-20 wt % alpha alumina;
- as well as having:
- a BET surface area of 50-60 m2/g, a total pore volume (PV) of 600-700 mL/kg as measured by mercury intrusion porosimetry.
Dependencies are inferred from the claim text.