Shear band having ultra-low hysteresis rubber
AssigneeCompagnie Generale Des Etablissements Michelin
InventorsClifford WILSON, Clayton BOHN, JR.
Life of this patent
Estimating the term…
Abstract
A shear band that may be used e.g., in a non-pneumatic tire is provided. The shear band uses interlaced reinforcing elements positioned within a shear layer of elastomeric material. A variety of configurations may be used to create the interlaced positioning of the reinforcing elements including e.g., a horizontal diamond or vertical diamond configuration. The shear layer formed from a rubber composition having a very low hysteresis reinforced with silica and carbon black and one or more anti-reversion chemical selected from 1,3 bis((3-methyl-2,5-dioxopyrrol-1-yl)methyl)benzene (CAS No.: 119462-56-5) and hexamethylene 1,6-bis(thiosulphate), disodium salt, dihydrate (CAS No.: 5719-73-3).
Claims15
An annular shear band defining axial, radial and circumferential directions, the annular shear band comprising:
- an annular shear layer constructed from a rubber composition;
- a plurality of discrete, annular reinforcing elements positioned along a plurality of axially-oriented rows throughout the annular shear layer, the reinforcing elements separated from one another by a predetermined distance, each reinforcing element having a centerpoint, wherein the reinforcing elements are interlaced along the axial or radial direction of the shear band such that the centerpoints of reinforcing elements of adjacent, axially-oriented rows are arranged to form a rhombus having non-orthogonal angles between sides of the rhombus, wherein the rubber composition is based upon a cross-linkable rubber composition, the cross-linkable rubber composition comprising, in parts by weight per 100 parts by weight of rubber (phr):
- between 50 phr and 100 phr of a natural rubber;
- between 0 phr and 50 phr of a second rubber component selected from the group consisting of polybutadiene rubber, a copolymer of polybutadiene and styrene wherein the copolymer has no more than 5 mol % styrene and combinations thereof;
- between 25 phr and 60 phr of a reinforcing fillers that is limited to a first portion that is a silica between 35 wt % and 70 wt % of the total reinforcing fillers and has a target surface area of between 40 m2/g and 55 m2/g and a second portion that is a carbon black between 30 wt % and 65 wt % of the total amount of the reinforcing fillers and has a target surface area of between 15 m2/g and 45 m2/g;
- between 0.5 phr and 2.5 phr an anti-reversion chemical hexamethylene 1,6-bis(thiosulphate), disodium salt, dihydrate and
- a sulfur cure system.
The annular shear band of any one of the above claims, wherein the reinforcing elements each have a nominal diameter Φ, and wherein adjacent, axially-oriented rows of the reinforcing elements are separated from each other by a predetermined distance, ws, in the range of between Φ/2 and Φ/10 or is Φ/4.
A non-pneumatic wheel comprising the annular shear band of any of the preceding claims.
Dependencies are inferred from the claim text.