Non-bipyridyl salt herbicide, preparation method therefor, and use thereof
AssigneesShanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai Tenth People’s Hospital
InventorsWenjun TANG, Ai PENG, Henian PENG, Dake ZHAO
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Abstract
A non-bipyridyl salt herbicide, a preparation method therefor, and a use thereof are provided. A diene diamine compound having the structure of formula (I) or a tricyclic diene piperazine structure represented by formula (II) specifically provided. The non-bipyridyl salt compound can be converted into paraquat or diquat under light and air conditions, has equivalent herbicidal properties to paraquat or diquat, and the toxicity thereof is not significant. Therefore, the non-bipyridyl salt compound can be used as an herbicide as a non-toxic substitute for paraquat or diquat.
Claims15
A use of a compound having a structure shown in Formula I or Formula II, a pesticide science acceptable salt, an enantiomer, a diastereomer, an optical isomer, a tautomer, a racemate, a deuterated derivative thereof, or a combination thereof, for the preparation of plant killing agents (preferably herbicides):
- wherein,
- R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 are each independently selected from the group consisting of:
- hydrogen, halogen, cyano, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 alkoxy, —C(O)O(C1-C6)alkyl, —S(O)p(C1-C6)alkyl, C1-C6 haloalkyl, C1-C6 haloalkoxy, and —NRaRb;
- p is 0, 1, or 2;
- Ra and Rb are each independently selected from the group consisting of:
- H, C1-C6 alkyl, C3-C6 cycloalkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 haloalkyl and C1-C6 alkoxy;
- R6′ and Ry′ are each independently selected from the group consisting of H, C1-C6 alkyl, and C1-C6 haloalkyl.
(canceled)
11-13. (canceled)
Dependencies are inferred from the claim text.