Method for producing superabsorbents
AssigneeBASF SE
InventorsMonte Alan PETERSON, Vernon Lynn ADEY, Jan Niclas GORGES, Juergen SCHROEDER
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Abstract
The present invention relates to a process for continuously producing superabsorbents, where an aqueous monomer solution is polymerized to a polymer gel, the acrylic acid present in the offgas from the polymerization and/or drying is scrubbed out by means of an aqueous solution, the pH of the aqueous solution is from 9.0 to 12.5 and the acrylic acid-laden aqueous solution is used at least partly for production of the monomer solution or metered into the polymerization in parallel with the monomer solution.
Claims14
A process for continuously producing superabsorbents, comprising:
- polymerizing an aqueous monomer solution comprising a partly neutralized acrylic acid to a polymer gel;
- optionally extruding the polymer gel;
- drying the polymer gel;
- and
- comminuting, classifying, and optionally thermally surface postcrosslinking the dried polymer gel;
- wherein:
- a water content of the aqueous monomer solution is 40% to 75% by weight;
- the acrylic acid has been neutralized to an extent of 40 to 85 mol %;
- acrylic acid present in an offgas from the polymerization and/or drying is scrubbed out with an aqueous solution;
- a pH of the aqueous solution is from 9.0 to 12.5;
- and
- the acrylic acid-laden aqueous solution is used at least partly for production of the monomer solution or metered into the polymerization in parallel with the monomer solution.
Dependencies are inferred from the claim text.