A method for the production of a bio-oil
AssigneeVotion Biorefineries AB
InventorAnders EDLING HULTGREN
Life of this patent
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Abstract
The present invention relates to a method for providing a bio-oil from biomass, wherein the method comprises the steps of:—adding a biomass with a lignin content of from 0 to 40 wt %;—adding a non-aqueous fluid;—adding a base comprising potassium N ions;—subjecting the mixture to thermal treatment at a temperature of from 100° C. to 320° C. to obtain a liquid comprising bio-oil;—adding an acid to precipitate salts;—subjecting the liquid comprising bio-oil to a temperature of from 10° C. to 320° C. to obtain a mixture comprising an aqueous phase and a bio-oil; and—removing the aqueous phase from the mixture to obtain a demetallized bio-oil;—whereby the demetallized bio-oil obtained has a total metal content of less than 200 ppm, and a total phosphorus content of less than 10 ppm.
Claims30
A method for providing a demetallized bio-oil, comprising the steps of:
- a) starting with a biomass with a lignin content of from 0 to 40 wt %;
- b) adding a non-aqueous fluid;
- c) adding a base comprising potassium ions, thereby obtaining a mixture comprising the biomass, the base, and the non-aqueous fluid;
- d) subjecting the mixture comprising the biomass, the base, and the non-aqueous fluid to thermal treatment at a temperature of 100° C. to 320° C. to obtain a liquid comprising bio-oil;
- e) adding an acid to the liquid comprising bio-oil to precipitate salt, and optionally washing the precipitated salt;
- f) optionally adding one or more of water, an acid, a bio-oil, or a solvent, to the bio-oil of step e) to obtain a mixture;
- g) subjecting the liquid obtained in step e), or the mixture obtained in step f), to a temperature of from 10° C. to 320° C. to obtain a second mixture comprising an aqueous phase and a bio-oil;
- h) removing the aqueous phase from the second mixture to obtain a demetallized bio-oil;
- i) optionally repeating steps f)-h);
- and
- j) optionally subjecting the demetallized bio-oil to hydroprocessing;
- whereby the demetallized bio-oil obtained has a total metal content of less than 200 ppm and a total phosphorus content of less than 10 ppm.
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Dependencies are inferred from the claim text.