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US 2026/0193575 A1Published application
Composition and process for electively etching a hard mask and/or an etch-stop layer in the presence of layers of low-k materials, copper, cobalt and/or tungsten
AssigneeBASF SE
InventorsJoannes Theodorus Valentinus HOOGBOOM, Andreas KLIPP, Jhih Jheng KE, Che Wei WANG, Chia Ching TING
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Abstract
Described herein are a cleaning composition, a wet-etch composition including the cleaning composition and one or more oxidants, and a method of using the wet-etch composition. Also described herein are a process for the manufacture of a semiconductor device from a semiconductor substrate and a kit including the cleaning composition and one or more oxidants.
Claims15
A cleaning composition, comprising at least the following components:
- (A) as solubilizer, one or more compounds of formula I:
- wherein R1 is selected from the group consisting of branched or unbranched alkyl having 1, 2, 3 or 4 carbon atoms;
- (B) one or more corrosion inhibitors, selected from the group consisting of benzotriazoles which are unsubstituted or substituted once or twice independently by branched or unbranched alkyl having 1, 2, 3 or 4 carbon atoms, aminoalkyl wherein the alkyl is branched or unbranched and has 1, 2, 3 or 4 carbon atoms, phenyl, thiophenyl, halogen, hydroxy, nitro and/or thiol, and mixtures thereof;
- (C) one or more polar, non-protogenic organic solvents
- wherein the one, or at least one of the more, or all of the more, polar, non-protogenic organic solvents (C) are selected from the group consisting of
- dimethyl formamide,
- dimethyl sulfoxide,
- dimethyl acetamide,
- N-methylpyrrolidone,
- propylene carbonate,
- tetrahydrofuran,
- 2-imidazolidinone which is substituted once or twice by a branched or unbranched alkyl group having 1 to 4 carbon atoms,
- and
- mixtures thereof;
- (D) water,
- and
- (E) one or more alkyl glycol ethers, in a total amount in the range of from 28 mass-% to 50 mass-%, relative to the total mass of the cleaning composition.
14 more elements
Dependencies are inferred from the claim text.