Organic electroluminescent dopant material and light-emitting device
AssigneeJilin OLED Optical and Electronic Materials Co., Ltd.
InventorsHui WANG, Xiaolong LI, Xingwang LANG, Weihan XU, Zhenyang LU, Sheng SUN, Haishan FEI
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Abstract
The present invention provides an organic electroluminescent dopant material and a light-emitting device. By introducing a deuterium atom group at a specific position on a thiophene ring and adjusting the molecular spacing and bond energy of the obtained compound, a dopant material having a specific atomic structure is obtained. After the obtained organic compound having a specific atomic structure is used in the organic electroluminescent device, the driving voltage is reduced, and the luminous efficiency of the device is improved.
Claims12
An organic electroluminescent dopant material, comprising a compound M(LA)2(LB), wherein M is a metal;
- LA and LB are both ligands, and LA and LB are compounds having the following general structural formulas:
- Ar1 and Ar2 are independently selected from any one of —F, —CN, —CH3, —CD3, —CT3, —CF3, —CH2F, —CHF2, —Ge(Me)3, —Si(Me)3, substituted or unsubstituted C2-C6 alkyl, substituted or unsubstituted C3-C20 cycloalkyl, substituted or unsubstituted C6-C10 aryl, and substituted or unsubstituted 4- to 8-membered aromatic heterocyclyl;
- R1, R2, R3, R4, R5, R6, R7, R8, and R9 are independently selected from any one of —H, —F, —CN, —CH3, —CD3, —CT3, —CF3, —CH2F, —CHF2, —Ge(Me)3, —Si(Me)3, substituted or unsubstituted C2-C6 alkyl, substituted or unsubstituted C3-C20 cycloalkyl, substituted or unsubstituted C6-C10 aryl, and substituted or unsubstituted 4- to 8-membered aromatic heterocyclyl;
- R10, R11, and R12 are independently selected from any one of —H, -D, -T, —F, —CN, —CH3, —CD3, —CT3, —CF3, —CH2F, —CHF2, —Ge(Me)3, —Si(Me)3, substituted or unsubstituted C2-C6 alkyl, substituted or unsubstituted C3-C20 cycloalkyl, substituted or unsubstituted C6-C10 aryl, and substituted or unsubstituted 4- to 8-membered aromatic heterocyclyl;
- the “substitution” means being capable of being substituted with —H, -D, -T, —F, —CN, —CH3, —CD3, —CT3, —CF3, —CH2F, —CHF2, —Ge(Me)3, —Si(Me)3, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl, thiocyclopentane, phenyl, biphenyl, terphenyl, naphthyl, fluorenyl, phenanthryl, anthracyl, indenyl, triphenylenyl, fluoranthenyl, furyl, thienyl, imidazolyl, pyrazolyl, thiazolyl, pyridinyl, pyrazinyl, pyrimidinyl, benzofuryl, benzothienyl, isobenzofuryl, dibenzofuryl, dibenzothienyl, benzimidazolyl, benzothiazolyl, benzisothiazolyl, benzothiadiazolyl, quinolyl, isoquinolyl, quinazolinyl, quinoxalinyl, and carbazolyl groups.
Dependencies are inferred from the claim text.