Back to results
US 2026/0184883 A1Published application
Depolymerization of polyisocyanurates with organic amine bases
AssigneeEvonik Operations GmbH
InventorsSarah Otto, Michael Suchan, Michael Ferenz, Christine Weiß
Life of this patent
Estimating the term…
Abstract
A process depolymerizes polyisocyanurate under mild conditions and low salt concentration in the reaction mixture, wherein valuable raw materials of the polyisocyanurate can be recovered in high yields and good quality, i.e. a quality allowing usage of the recycled raw materials for production of new polyurethanes, preferably polyurethane foam, or polyisocyanurates, preferably polyisocyanurate foams.
Claims23
A method of hydrolyzing a polyisocyanurate, comprising:
- producing the polyisocyanurate by reacting one or more polyol(s) selected from the group consisting of polyesterpolyol, a mixture of polyesterpolyols and a mixture of polyester- and polyetherpolyols, with an excess of one or more isocyanate(s) selected from the group consisting of organic isocyanate, a mixture of organic isocyanates, organic polyisocyanate a mixture of organic polyisocyanates and a mixture of organic isocyanate(s) and organic polyisocyanate(s), and
- bringing into contact the polyisocyanurate with water in presence of an organic amine base to yield one or more carboxylic acid(s) comprising equal to or more than 2 carboxylic acid groups per molecule and corresponding to the carboxylic acid(s) used to prepare the polyesterpolyol(s) that was/were used to prepare the polyisocyanurate, and one or more polyol(s) corresponding to the polyol(s) used to prepare the polyesterpolyol(s) that was/were used to prepare the polyisocyanurate, and one or more organic amine and/or polyamine, which correspond(s) to the organic isocyanate or polyisocyanate used to prepare the polyisocyanurate, and
- wherein the reaction mixture comprising the polyisocyanurate, water and the organic amine base is a stirred homogeneous or heterogeneous mixture during hydrolysis.
Dependencies are inferred from the claim text.