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US 2026/0167867 A1Published application
Liquid crystal compounds
AssigneeRolic Technologies AG
InventorsSabrina CHAPPELLET, Tobias VON ARX
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Abstract
The invention relates to novel polymerizable liquid crystals of formula (I), to liquid crystal polymer (LCP) mixtures comprising these compounds, and to their uses for optical and electro-optical devices, wherein a compound of formula (I) is as follows: In particular, the invention relates to substituted curable LCPs with high optical anisotropy and the use of such LCPs in the preparation of substantially uniform or patterned film in which the orientation of the LCP molecules can be controlled.
Claims15
A compound of formula (I)
- wherein
- A and B each independently from each other represents an unsubstituted or substituted carbocyclic or heterocyclic aromatic group selected from a monocyclic ring of five or six atoms, two adjacent monocyclic rings of five or six atoms, a bicyclic ring system of eight, nine or ten atoms, or a tricyclic ring system of thirteen or fourteen atoms;
- SP1, SP2 and SP3 each independently from each other represents a substituted or unsubstituted, straight-chain or branched C3-C18 alkylene group, in which one, two, three or four more CH2, CH or C groups are unreplaced or replaced by groups selected from the group consisting of —CH═CH—, —C≡C—, —O—, —S—, —NR′CO—, —COO—, —OOC—, —CONR′—, —OCOO—, —OCONR′ with the proviso that the spacer group does not contain two adjacent heteroatoms;
- X1, X2, X3 and X4 each independently from each other is selected from the group consisting of —O—, —S—, —NR′—, —CO—, —COO—, —OOC—, —CONR′—, —OCOO—, —OCONR′ and a single bond;
- R′ is selected from the group consisting of hydrogen, a C1-C18alkyl group;
- BP1 and BP2 each independently from each other represents a polymerizable group,
- A1, A2, A3 and A4 each independently from each other are selected from the group consisting of hydrogen, —OR, —COOR, —OCOR, —CONR, —OCOOR, —OCONR and a C1-C18alkyl group, wherein
- R is selected from the group consisting of hydrogen, an unsubstituted or substituted carbocyclic or heterocyclic aromatic group selected from a monocyclic ring of five or six atoms, two adjacent monocyclic rings of five or six atoms, a bicyclic ring system of eight, nine or ten atoms, or a tricyclic ring system of thirteen or fourteen atoms;
- a substituted or unsubstituted, straight-chain or branched C3-18alkyl group, in which one, two, three or four more CH2, CH or C groups are unreplaced or replaced by groups selected from the group consisting of —CH═CH—, —C≡C—, —O—, —S—, —NR″CO—, —COO—, —OOC—, —CONR″—, —OCOO—, —OCONR″ with the proviso that the spacer group does not contain two adjacent heteroatoms, wherein R″ is selected from the group consisting of hydrogen, a C1-C18alkyl group.
6 more elements
Dependencies are inferred from the claim text.