Process for the production of a high molecular weight polyester (co)polymer
AssigneeAvantium Knowledge Centre B.V.
InventorsKevin van der Maas, Bing Wang, Robert-Jan Van Putten, Gerardus Johannes Maria Gruter
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AssigneeAvantium Knowledge Centre B.V.
InventorsKevin van der Maas, Bing Wang, Robert-Jan Van Putten, Gerardus Johannes Maria Gruter
Estimating the term…
The invention relates to a process for the production of a (high molecular weight) polyester (co)polymer. The process includes (a) adding a diphenyl oxalate ester to a starting polyester (co)polymer at least comprising alcohol end groups and units derived from 1,2-diols, wherein the phenyl group in the diphenyl oxalate ester is optionally substituted; and (b) in case the temperature is not already higher than 220° C., elevating the temperature of the mixture resulting from step (a) to at least 220° C., and reducing the pressure, for a period of time sufficient to obtain a polyester (co)polymer product wherein the amount of oxalate units that remain in the (co)polymer is less than added in the form of the diphenyl oxalate ester; and no or less than 1 mole % oxalate units are present, the percentage relative to a total amount of monomer units.
A process for the production of a (high molecular weight) polyester (co)polymer, comprising
Dependencies are inferred from the claim text.