Method for producing oligofuran compound containing reactive silyl group, and oligofuran compound containing reactive silyl group
AssigneeNational University Corporation Gunma University
InventorsYuya TACHIBANA, Shunsuke BEPPU, Ken-ichi KASUYA
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Abstract
Provided is a method of producing a dihydrosilyloligofuran compound, the method including: a deprotonation step of deprotonating an oligofuran compound in the presence of a deprotonating agent; and a silylation step of allowing a deprotonated product of the oligofuran compound to react with a halohydrosilane compound, in which method the oligofuran compound is a di- to 256-mer of a monofuran compound.
Claims9
A method of producing a dihydrosilyloligofuran compound, the method comprising:
- a deprotonation step of deprotonating an oligofuran compound in the presence of a deprotonating agent;
- and
- a hydrosilylation step of allowing a deprotonated product of the oligofuran compound to react with a halohydrosilane compound,
- wherein the oligofuran compound is a di- to 256-mer of a monofuran compound.
A reactive silyl group-containing oligofuran compound represented by the following Formula (C′-1) or (D′-1):
- wherein, R1a and R2a each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- when R1a and R2a are each the optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or the optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms, R1a and R2a are optionally bound to each other via a direct bond or a linking group to form a ring;
- R5a and R6a each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- Y1a represents —CH2—, —CHR7a-, —C(R7a)2-, —PR7a—, —S—, —O—, —Si(R7a)2-, —NR7a-, or —C═C—;
- R7as each independently represent a hydrocarbon group having 1 to 8 carbon atoms;
- p represents an integer of 0 to 256;
- q represents an integer of 0 to 128;
- p+2q is an integer of 2 to 256;
- R's each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- and R10s each independently represent a hydroxy group, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms.
A reactive silyl group-containing bifuran compound represented by the following Formula (C-1), (C-2), (D-1), or (D-2):
- wherein, R1 to R4 each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- when R1 and R2 are each the optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or the optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms, R1 and R2 are optionally bound to each other via a direct bond or a linking group to form a ring;
- when R3 and R4 are each the optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or the optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms, R3 and R4 are optionally bound to each other via a direct bond or a linking group to form a ring;
- R5 and R6 each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- Y represents —CH2—, —CHR7—, —C(R7)2—, —PR7—, —S—, —O—, —Si(R7)2—, —NR7—, or —C═C—;
- R7s each independently represent a hydrocarbon group having 1 to 8 carbon atoms;
- R's each independently represent a hydrogen atom, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms;
- and R10s each independently represent a hydroxy group, an optionally substituted hydrocarbon group having 1 to 20 carbon atoms, or an optionally substituted hydrocarbonoxy group having 1 to 20 carbon atoms.
Dependencies are inferred from the claim text.