# US 2026/0133508 A1 · Electrophotographic photoreceptor, process cartridge, and image forming apparatus

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- Number: US 2026/0133508 A1
- Document ID: US20260133508A1
- Status: Published application
- Kind: A1
- Application number: 19/351,253
- Filed: 2025-10-06
- Published: 2026-05-14
- Earliest claimed: 2024-11-11
- Assignees: FUJIFILM Business Innovation Corp.
- Applicants: FUJIFILM Business Innovation Corp.
- Inventors: Masahiro IWASAKI; Tomoya SASAKI; Kenta IDE; Yoichi KIGOSHI; Fuyuki KANO; Yuki OYAMADA; Kohei TAKAOKA; Kosuke NARITA
- Web page: https://patentgrep.com/patent/US20260133508A1

## CPC

- G03G 5/056: {Polyesters}
- C08L 67/03: the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
- C08L 69/00: Compositions of polycarbonates; Compositions of derivatives of polycarbonates
- G03G 5/04: Photoconductive layers; Charge-generation layers or charge-transporting layers; Additives therefor; Binders therefor
- G03G 5/047: characterised by the charge-generation layers or charge transport layers {(G03G5/0433 and G03G5/0436 take precedence)}
- G03G 5/0564: {Polycarbonates}
- G03G 5/0605: {Carbocyclic compounds}
- G03G 21/0017: {Details relating to the internal structure or chemical composition of the blades}
- G03G 21/1814: {Details of parts of process cartridge, e.g. for charging, transfer, cleaning, developing (G03G21/1835 takes precedence)}
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

An electrophotographic photoreceptor includes a conductive substrate, a charge generation layer disposed on the conductive substrate, and a charge transport layer disposed on the charge generation layer, in which the charge transport layer contains a phenolic compound, a polyarylate resin, a polycarbonate resin, and a charge transport material, and each of a vector distance DISHT (J/cm3)1/2 between an HSP value of the charge transport material and an HSP value of the polyarylate resin, and a vector distance DISPC (J/cm3)1/2 between the HSP value of the polycarbonate resin and the HSP value of the polyarylate resin, which are calculated based on a Hansen solubility parameter, satisfies Expression (1) and Expression (2), D ⁢ I ⁢ S H ⁢ T ≤ 3.9 , Expression ⁢ ( 1 ) 9.2 ≤ D ⁢ I ⁢ S P ⁢ C < 1 ⁢ 2 . 0 . Expression ⁢ ( 2 )

## Claims

### Claim 1

An electrophotographic photoreceptor comprising:
a conductive substrate;
a charge generation layer disposed on the conductive substrate; and
a charge transport layer disposed on the charge generation layer,
wherein the charge transport layer contains a phenolic compound, a polyarylate resin, a polycarbonate resin, and a charge transport material, and each of a vector distance DISHT (J/cm3)1/2 between an HSP value of the charge transport material and an HSP value of the polyarylate resin, and a vector distance DISPC (J/cm3)1/2 between the HSP value of the polycarbonate resin and the HSP value of the polyarylate resin, which are calculated based on a Hansen solubility parameter, satisfies Expression (1) and Expression (2),
D
⁢
I
⁢
S
H
⁢
T
≤
3.9
,
Expression
⁢
(
1
)
9.2
≤
D
⁢
I
⁢
S
P
⁢
C
<
1
⁢
2
.
0
.
Expression
⁢
(
2
)

### Claim 2 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein a vector distance DISOHCT (J/cm3)1/2 between an HSP value of the phenolic compound and the HSP value of the charge transport material, which are calculated based on a Hansen solubility parameter, satisfies Expression (3),
3.
6
≤
D
⁢
I
⁢
S
OHCT
≤
7
.
0
.
Expression
⁢
(
3
)

### Claim 3 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein a vector distance DISOHPA (J/cm3)1/2 between an HSP value of the phenolic compound and the HSP value of the polyarylate resin, which are calculated based on a Hansen solubility parameter, satisfies Expression (4),
5
.
5
≤
D
⁢
I
⁢
S
OHPA
≤
8.
.
Expression
⁢
(
4
)

### Claim 4 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein a hydrogen bonding term δHOH (J/cm3)1/2 of the phenolic compound, which is calculated based on a Hansen solubility parameter, satisfies Expression (5),
3.
5
≤
δ
⁢
H
O
⁢
H
≤
7
.
7
.
Expression
⁢
(
5
)

### Claim 5 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein the phenolic compound includes a hindered phenolic compound.

### Claim 6 (depends on 5)

The electrophotographic photoreceptor according to claim 5,
wherein the phenolic compound includes a phenolic compound having 3 or fewer phenolic functional groups and a molecular weight of 300 or more.

### Claim 7 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein the polyarylate resin has a dicarboxylic acid unit represented by Formula (A) and a diol unit represented by Formula (B),
in Formula (A), ArA1 and ArA2 are each independently an aromatic ring which may have a substituent, LA is a single bond or a divalent linking group, and nA1 is 0, 1, or 2,
in Formula (B), ArB1 and ArB2 are each independently an aromatic ring which may have a substituent, LB is a single bond, an oxygen atom, a sulfur atom, or —C(Rb1)(Rb2)—, and nB1 is 0, 1, or 2, where Rb1 and Rb2 are each independently a hydrogen atom, an alkyl group having 1 or more and 20 or less carbon atoms, an aryl group having 6 or more and 12 or less carbon atoms, or an aralkyl group having 7 or more and 20 or less carbon atoms, and Rb1 and Rb2 may be bonded to each other to form a cyclic alkyl group.

### Claim 8 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein the polyarylate resin and the polycarbonate resin each have a constitutional unit including biphenyl represented by Formula (BP),
in Formula (BP), j is an integer of 0 or greater and 4 or less, j pieces of R1's are each independently a methyl group or an ethyl group, k is an integer of 0 or greater and 4 or less, and k pieces of R2's are each independently a methyl group or an ethyl group.

### Claim 9 (depends on 1)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 1,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 10 (depends on 2)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 2,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 11 (depends on 3)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 3,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 12 (depends on 4)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 4,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 13 (depends on 5)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 5,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 14 (depends on 6)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 6,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 15 (depends on 7)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 7,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 16 (depends on 8)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 8,
wherein the process cartridge is attachable to and detachable from an image forming apparatus.

### Claim 17 (depends on 1)

An image forming apparatus comprising:
the electrophotographic photoreceptor according to claim 1;
a charging device that charges a surface of the electrophotographic photoreceptor;
an electrostatic latent image forming device that forms an electrostatic latent image on the charged surface of the electrophotographic photoreceptor;
a developing device that develops the electrostatic latent image formed on the surface of the electrophotographic photoreceptor with a developer containing a toner to form a toner image; and
a transfer device that transfers the toner image to a surface of a recording medium.

### Claim 18 (depends on 17)

The image forming apparatus according to claim 17, further comprising:
a cleaning device that has a cleaning blade coming into contact with the surface of the electrophotographic photoreceptor and cleans the surface of the electrophotographic photoreceptor.

### Claim 19 (depends on 18)

The image forming apparatus according to claim 18,
wherein a contact portion of the cleaning blade coming into contact with the electrophotographic photoreceptor contains a polyurethane rubber obtained by polymerizing at least a polyol component and a polyisocyanate component, and the contact portion is formed of a member having a ratio M100/Re of a 100% modulus M100 (MPa) to a rebound resilience Re (%) of 0.25 or more, the rebound resilience Re of less than 25%, and a tensile stress at a 200% strain of 15 MPa or more.

### Claim 20 (depends on 19)

The image forming apparatus according to claim 19,
wherein the ratio M100/Re is 0.28 or more and 1.0 or less.
