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US 2026/0110967 A1Published application
Sulfonium salt monomer, polymer, chemically amplified resist composition, and pattern forming process
AssigneeShin-Etsu Chemical Co., Ltd.
InventorMasahiro Fukushima
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Abstract
A sulfonium salt monomer consists of a sulfonium cation having pentafluorosulfanyl and hydrocarbyloxycarbonyl groups and an aromatic sulfonic acid anion having a polymerizable group. A resist composition comprising a polymer comprising repeat units derived from the monomer exhibits a high solvent solubility, high sensitivity and high contrast and forms a small-size pattern having satisfactory lithography properties such as LWR, CDU, EL and DOF.
Claims15
A sulfonium salt monomer having the formula (A):
- wherein n1 is 0 or 1, n2 is 0, 1 or 2, n3 is 0, 1 or 2, n4 is 0, 1 or 2, n1 to n4 are in the range:
- 0≤n2+n3+n4≤5 when n1=0 and 0≤n2+n3+n4≤7 when n1=1;
- n5 is 0 or 1, n6 is 0, 1 or 2, n7 is 0, 1 or 2, n8 is 0, 1 or 2, n5 to n8 are in the range:
- 0≤n6+n7+n8≤5 when n5=0 and 0≤n6+n7+n8≤7 when n5=1;
- n9 is 0 or 1, n10 is 0, 1 or 2, n11 is 0, 1 or 2, n12 is 0, 1 or 2, n9 to n12 are in the range:
- 0≤n10+n11+n12≤5 when n9=0 and 0≤n10+n11+n12≤7 when n9=1, and 1≤n2+n6+n10≤6 and 1≤n3+n7+n11≤6,
- R1, R2 and R3 are each independently a C1-C20 hydrocarbyl group which may contain a heteroatom, two R1 may be identical or different when n3=2, two R2 may be identical or different when n7=2, two R3 may be identical or different when n11=2,
- R4, R5 and R6 are each independently halogen, nitro, hydroxy, carboxy, a C1-C20 hydrocarbyl group which may contain a heteroatom, a C1-C20 hydrocarbyloxy group which may contain a heteroatom, or a C1-C20 hydrocarbylthio group which may contain a heteroatom;
- when n4=2, two R4 may be identical or different and bond together to form a ring with the carbon atoms to which they are attached;
- when n8=2, two R5 may be identical or different and bond together to form a ring with the carbon atoms to which they are attached;
- when n12=2, two R6 may be identical or different and bond together to form a ring with the carbon atoms to which they are attached;
- two of three aromatic rings bonded to S+ may bond together to form a ring with the sulfur atom to which they are attached, and
- Z− is an aromatic sulfonate anion having a polymerizable group.
10 more elements
Dependencies are inferred from the claim text.