Herbicide/safener combination based on safeners from the class of substituted [(1,5- diphenyl-1h-1,2,4-triazol-3-yl)oxy]acetic acids and their salts

A herbicide/safener combination comprising one or more compounds effective as safener [component (A)] and one or more herbicidally active compounds [component (B)],

• where component (A) represents one or more compounds of general formula (I) or agrochemically acceptable salts thereof
• and in which
• (R1)n-phenyl represents Q-1.1 to Q-1.53 groups selected from:
• Q-1.1
• Q-1.2
• Q-1.3
• Q-1.4
• Q-1.5
• Q-1.6
• Q-1.7
• Q-1.8
• Q-1.9
• Q-1.10
• Q-1.11
• Q-1.12
• Q-1.13
• Q-1.14
• Q-1.15
• Q-1.16
• Q-1.17
• Q-1.18
• Q-1.19
• Q-1.20
• Q-1.21
• Q-1.22
• Q-1.23
• Q-1.24
• Q-1.25
• Q-1.26
• Q-1.27
• Q-1.28
• Q-1.29
• Q-1.30
• Q-1.31
• Q-1.32
• Q-1.33
• Q-1.34
• Q-1.35
• Q-1.36
• Q-1.37
• Q-1.38
• Q-1.39
• Q-1.40
• Q-1.41
• Q-1.42
• Q-1.43
• Q-1.44
• Q-1.45
• Q-1.46
• Q-1.47
• Q-1.48
• Q-1.49
• Q-1.50
• Q-1.51
• Q-1.52
• Q-1.53
• and (R2)m-phenyl represents Q-2.1 to Q-2.53 groups selected from:
• Q-2.1
• Q-2.2
• Q-2.3
• Q-2.4
• Q-2.5
• Q-2.6
• Q-2.7
• Q-2.8
• Q-2.9
• Q-2.10
• Q-2.11
• Q-2.12
• Q-2.13
• Q-2.14
• Q-2.15
• Q-2.16
• Q-2.17
• Q-2.18
• Q-2.19
• Q-2.20
• Q-2.21
• Q-2.22
• Q-2.23
• Q-2.24
• Q-2.25
• Q-2.26
• Q-2.27
• Q-2.28
• Q-2.29
• Q-2.30
• Q-2.31
• Q-2.32
• Q-2.33
• Q-2.34
• Q-2.35
• Q-2.36
• Q-2.37
• Q-2.38
• Q-2.39
• Q-2.40
• Q-2.41
• Q-2.42
• Q-2.43
• Q-2.44
• Q-2.45
• Q-2.46
• Q-2.47
• Q-2.48
• Q-2.49
• Q-2.50
• Q-2.51
• Q-2.52
• Q-2.53
• R3 represents hydrogen,
• and
• R4 is one of hydrogen, methyl, ethyl, n-propyl, i-propyl, n-butyl, n-pentyl, phenyl, benzyl, CH2(4-Cl-Ph), CH2(4-F-Ph), CH2(4-OMe-Ph), 2-methoxyethyl, tetrahydrofuran-2-ylmethyl, tetrahydrofuran-3-ylmethyl, tetrahydropyran-2-ylmethyl, tetrahydropyran-3-ylmethyl, tetrahydropyran-4-ylmethyl, methylpropionate-3-yl, ethylpropionate-3-yl, methylacetate-2-yl, ethylacetate-2-yl, methylpivalate-2-yl, ethylpivalate-3-yl, methyl-2-methylpropanoate-3-yl, methyl-2,2-dimethylpropanoate-3-yl, ethyl-2-methylpropanoate-3-yl, methyl-2-propanoate-2-yl, ethyl-2-propanoate-2-yl, methylacetate-2-yl, ethylacetate-2-yl, methyl-1-methylcyclopropanecarboxylate-2-yl, ethyl-1-methylcyclopropanecarboxylate-2-yl, 2-(dimethylamino)ethyl, oxetan-3-yl, (3-methyloxetan-3-yl)methyl, 2,2,2-trifluoroethyl, 2,2-difluoroethyl, 2-fluoroethyl, 2,2,3,3,3-pentafluoropropyl, cyclopropylmethyl, 1-cyclopropylethyl, (1-methylcyclopropyl)methyl, (2,2-dichlorocyclopropyl)methyl, (2,2-dimethylcyclopropyl)methyl, allyl, propargyl (prop-2-yn-1-yl), 2-chloroprop-2-en-1-yl, 3-phenylprop-2-yn-1-yl, 3,3-dichloroprop-2-en-1-yl, 3,3-dichloro-2-fluoroprop-2-en-1-yl, methylprop-2-yn-1-yl, 2-methylprop-2-en-1-yl, but-2-en-1-yl, but-3-en-1-yl, but-2-yn-1-yl, but-3-yn-1-yl, 4-chlorobut-2-yn-1-yl, 3-methyl-but-2-en-1-yl, 3-methyl-but-1-en-1-yl, 1-(2E)-1-methylbut-2-en-1-yl, (E)-pent-3-en-2-yl and (Z)-pent-3-en-2-yl, cyclobutylmethyl, cyclopentylmethyl, cyclohexylmethyl, heptan-2-yl, isobutyl, 1,3-dioxolan-2-ylmethyl or 1-ethyl-5-methyl-1H-pyrazole-4-methyl,
• and
• where component (B) represents one or more compounds of general formula (II),
• in which
• A is N or CY,
• X is one of a nitro, a halogen, cyano, formyl, thiocyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C3-C6)-alkynyl, (C3-C6)-cycloalkyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, halo-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(O)N(R1)2, NR1C(O)N(R1)2, OC(O)N(R1)2, C(O)NR1OR1, OR1, OCOR1, OSO2R2, S(O)nR2, SO2OR1, SO2N(R1)2, NR1SO2R2, NR1COR1, (C1-C6)-alkyl-S(O)nR2, (C1-C6)-alkyl-OR1, (C1-C6)-alkyl-OCOR1, (C1-C6)-alkyl-OSOR2, (C1-C6)-alkyl-CO2R1, (C1-C6)-alkyl-SO2OR1, (C1-C6)-alkyl-CON(R1)2, (C1-C6)-alkyl-SO2N(R1)2, (C1-C6)-alkyl-NR1COR1, (C1-C6)-alkyl-NR1SO2R2, NR1R2, P(O)(OR5)2, CH2P(O)(OR5)2, (C1-C6)-alkylheteroaryl, and (C1-C6)-alkylheterocyclyl, where the latter two radicals are each substituted by s radicals selected from the group consisting of a halogen, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, S(O)n—(C1-C6)-alkyl, (C1-C6)-alkoxy and halo-(C1-C6)-alkoxy, and where heterocyclyl comprises n oxo groups,
• Y is one of hydrogen, nitro, a halogen, cyano, thiocyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, halo-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(O)N(R1)2, NR1C(O)N(R1)2, OC(O)N(R1)2, CO(NOR1)R1, NR1SO2R2, NR1COR1, OR1, OSO2R2, S(O)nR2, SO2OR1, SO2N(R1)2, (C1-C6)-alkyl-S(O)nR2, (C1-C6)-alkyl-OR1, (C1-C6)-alkyl-OCOR1, (C1-C6)-alkyl-OSO2R2, (C1-C6)-alkyl-CO2R1, (C1-C6)-alkyl-CN, (C1-C6)-alkyl-SO2OR1, (C1-C6)-alkyl-CON(R1)2, (C1-C6)-alkyl-SO2N(R1)2, (C1-C6)-alkyl-NR1COR1, (C1-C6)-alkyl-NR1SO2R2, N(R1)2, P(O)(OR5)2, CH2P(O)(OR5)2, (C1-C6)-alkylphenyl, (C1-C6)-alkylheteroaryl, (C1-C6)-alkylheterocyclyl, phenyl, heteroaryl and heterocyclyl, where the latter six radicals are each substituted by s radicals selected from the group consisting of a halogen, nitro, cyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n—(C1-C6)-alkyl, (C1-C6)-alkoxy, halo-(C1-C6)-alkoxy, (C1-C6)-alkoxy-(C1-C4)-alkyl and cyanomethyl, and where heterocyclyl comprises n oxo groups,
• Z is one of a halogen, cyano, thiocyano, halo-(C1-C6)-alkyl, (C2-C6)-alkenyl, halo-(C2-C6)-alkenyl, (C2-C6)-alkynyl, halo-(C2-C6)-alkynyl, (C3-C6)-cycloalkyl, halo-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, halo-(C3-C6)-cycloalkyl-(C1-C6)-alkyl, COR1, COOR1, OCOOR1, NR1COOR1, C(O)N(R1)2, NR1C(O)N(R1)2, OC(O)N(R1)2, C(O)NR1OR1, OSO2R2, S(O)nR2, SO2OR1, SO2N(R1)2, NR1SO2R2, NR1COR1, (C1-C6)-alkyl-S(O)nR2, (C1-C6)-alkyl-OR1, (C1-C6)-alkyl- OCOR1, (C1-C6)-alkyl-OSO2R2, (C1-C6)-alkyl-CO2R1, (C1-C6)-alkyl-SO2OR1, (C1-C6)-alkyl-CON(R1)2, (C1-C6)-alkyl-SO2N(R1)2, (C1-C6)-alkyl-NR1COR1, (C1-C6)-alkyl-NR1SO2R2, N(R1)2, P(O)(OR5)2, heteroaryl, heterocyclyl and phenyl, where the three latter radicals are each substituted by s radicals selected from the group consisting of a halogen, nitro, cyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n—(C1-C6)-alkyl, (C1-C6)-alkoxy or halo-(C1-C6)-alkoxy, and where heterocyclyl comprises n oxo groups,
• or
• Z is one of hydrogen, (C1-C6)-alkyl and (C1-C6)-alkoxy if Y is the S(O)nR2 radical,
• R is one of (C1-C8)-alkyl, halo-(C1-C8)-alkyl, (C2-C8)-alkenyl, halo-(C2-C8)-alkenyl, (C2-C8)-alkynyl, and halo-(C2-C8)-alkynyl, where these six aforementioned radicals are each substituted by s radicals selected from the group consisting of hydroxy, nitro, cyano, SiR53, PO(OR5)2, S(O)n—(C1-C6)-alkyl, S(O)n—(C1-C6)-haloalkyl, (C1-C6)-alkoxy, halo-(C1-C6)-alkoxy, N(R3)2, COR3, COOR3, OCOR3, NR3COR3, NR3SO2R4, O(C1-C2)-alkyl-(C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl, heteroaryl, heterocyclyl, and phenyl, where the three latter radicals are each substituted by s radicals selected from the group consisting of methyl, ethyl, methoxy, trifluoromethyl, cyano and a halogen, and where heterocyclyl comprises n oxo groups,
• or
• R is one of (C3-C7)-cycloalkyl, heteroaryl, heterocyclyl and phenyl, each substituted by s radicals selected from the group consisting of a halogen, nitro, cyano, (C1-C6)-alkyl, halo-(C1-C6)-alkyl, (C3-C6)-cycloalkyl, S(O)n—(C1-C6)-alkyl, (C1-C6)-alkoxy, halo-(C1-C6)-alkoxy and (C1-C6)-alkoxy-(C1-C4)-alkyl, where heterocyclyl comprises n oxo groups,
• R1 is one of hydrogen, (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkyl-(C3-C6)-cycloalkyl, (C1-C6)-alkyl-O—(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, phenyl, phenyl-(C1-C6)-alkyl, heteroaryl, (C1-C6)-alkylheteroaryl, heterocyclyl, (C1-C6)-alkylheterocyclyl, (C1-C6)-alkyl-O-heteroaryl, (C1-C6)-alkyl-O-heterocyclyl, (C1-C6)-alkyl-NR3-heteroaryl and (C1-C6)-alkyl-NR3-heterocyclyl, where the 21 latter radicals are each substituted by s radicals selected from the group consisting of cyano, nitro, thiocyano, OR3, S(O)nR4, N(R3)2, NR3OR3, COR3, OCOR3, SCOR4, NR3COR3, NR3SO2R4, CO2R3, COSR4, CON(R3)2 and (C1-C4)-alkoxy-(C2-C6)-alkoxycarbonyl, and where heterocyclyl comprises n oxo groups,
• R2 is one of (C1-C6)-alkyl, (C1-C6)-haloalkyl, (C2-C6)-alkenyl, (C2-C6)-haloalkenyl, (C2-C6)-alkynyl, (C2-C6)-haloalkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkenyl, (C3-C6)-halocycloalkyl, (C1-C6)-alkyl-O—(C1-C6)-alkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl, phenyl, phenyl-(C1-C6)-alkyl, heteroaryl, (C1-C6)-alkylheteroaryl, heterocyclyl, (C1-C6)-alkylheterocyclyl, (C1-C6)-alkyl-O-heteroaryl, (C1-C6)-alkyl-O-heterocyclyl, (C1-C6)-alkyl-NR3-heteroaryl and (C1-C6)-alkyl-NR3-heterocyclyl, where the 21 latter radicals are each substituted by s radical selected from the group consisting of cyano, a halogen, nitro, thiocyano, OR3, S(O)nR4, N(R3)2, NR3OR3, COR3, OCOR3, SCOR4, NR3COR3, NR3SO2R4, CO2R3, COSR4, CON(R3)2 and (C1-C4)-alkoxy-(C2-C6)-alkoxycarbonyl, and where heterocyclyl comprises n oxo groups,
• R3 is one of hydrogen, (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl and phenyl,
• R4 is one of (C1-C6)-alkyl, (C2-C6)-alkenyl, (C2-C6)-alkynyl, (C3-C6)-cycloalkyl, (C3-C6)-cycloalkyl-(C1-C6)-alkyl and phenyl,
• R5 is (C1-C4)-alkyl,
• n is 0, 1 or 2, and
• s is 0, 1, 2 or 3.