Copper-coated titanium diboride articles
AssigneeAlcoa USA Corp.
InventorsXinghua Liu, Benjamin D. Mosser
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Abstract
New copper-coated titanium diboride electrodes are disclosed. The copper-coated titanium diboride electrodes may be used in an aluminum electrolysis cell. In one embodiment, a method includes installing the copper-coated titanium diboride electrode in the aluminum electrolysis cell and operating the aluminum electrolysis cell. During start-up, the aluminum electrolysis cell may be preheated and a bath may be formed from a molten electrolyte. Alumina (Al2O3) may in the added to the bath and reduced to aluminum metal. At least some of the copper film of the copper-coated titanium diboride electrode may be replaced by an aluminum film, thereby forming an aluminum-wetted titanium diboride electrode.
Claims20
A product comprising:
- (a) a titanium diboride electrode, wherein the titanium diboride electrode comprises:
- (i) a density of from 80% to 99% of theoretical, and
- (ii) an apparent porosity of from 0.01% to 20%;
- and
- (b) a copper-based film disposed on at least a portion of the titanium diboride electrode;
- wherein the copper-based film predominately comprises copper.
Dependencies are inferred from the claim text.