# US 2026/0100348 A1 · Positive electrode, rechargeable lithium battery including the same, and method of manufacturing the same

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2026/0100348 A1
- Document ID: US20260100348A1
- Status: Published application
- Kind: A1
- Application number: 19/345,665
- Filed: 2025-09-30
- Published: 2026-04-09
- Earliest claimed: 2024-10-08
- Assignees: Samsung SDI Co., Ltd.
- Applicants: Samsung SDI Co., Ltd.
- Inventors: Minah CHA; Hoseong HWANG; Jongjin LEE; JinYoung KIM
- Web page: https://patentgrep.com/patent/US20260100348A1

## CPC

- H01M 4/131: Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- C01G 53/42: containing alkali metals, e.g. LiNiO2
- H01M 4/0404: {by coating on electrode collectors}
- H01M 4/1391: of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
- H01M 4/364: {as mixtures}
- H01M 4/366: {as layered products}
- H01M 4/525: of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
- H01M 4/625: {Carbon or graphite}
- H01M 10/052: Li-accumulators
- C01P 2002/54: one element only
- C01P 2004/03: obtained by SEM
- C01P 2006/40: Electric properties
- H01M 2004/028: {Positive electrodes}
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Disclosed are positive electrodes, rechargeable lithium batteries including the positive electrode, and methods of manufacturing the positive electrode. The positive electrode includes a current collector and a positive electrode active material layer on the current collector. The positive electrode active material layer comprises a first positive electrode active material that comprises lithium-nickel-based composite oxide and has a bare form without a carbon coating on a surface thereof, a second positive electrode active material that comprises lithium-nickel-based composite oxide and has a core and a carbon coating layer on the core, a conductive material that comprises a carbon-based material, and a binder.

## Claims

### Claim 1

A positive electrode, comprising:
a current collector; and
a positive electrode active material layer on the current collector,
wherein the positive electrode active material layer comprises:
a first positive electrode active material that comprises a lithium-nickel-based composite oxide, the first positive electrode active material having a bare form without a carbon coating on a surface thereof;
a second positive electrode active material that comprises a lithium-nickel-based composite oxide, the second positive electrode active material comprising a core and a carbon coating layer on the core;
a conductive material that comprises a carbon-based material; and
a binder.

### Claim 2 (depends on 1)

The positive electrode as claimed in claim 1, wherein the first positive electrode active material comprises at least one selected from among a large particle and a small particle.

### Claim 3 (depends on 1)

The positive electrode as claimed in claim 1, wherein the second positive electrode active material comprises at least one selected from among a large particle and a small particle.

### Claim 4 (depends on 1)

The positive electrode as claimed in claim 1, wherein
the core comprises the lithium-nickel-based composite oxide, and
the carbon coating layer comprises graphene.

### Claim 5 (depends on 1)

The positive electrode as claimed in claim 1, wherein the carbon coating layer is on a portion of a surface of the core.

### Claim 6 (depends on 1)

The positive electrode as claimed in claim 1, wherein the carbon coating layer exposes a portion of a surface of the core.

### Claim 7 (depends on 1)

The positive electrode as claimed in claim 1, wherein a total amount of the first positive electrode active material and the second positive electrode active material is in a range of about 97 wt % to about 99.5 wt % based on a total weight of 100 wt % of the positive electrode active material layer.

### Claim 8 (depends on 1)

The positive electrode as claimed in claim 1, wherein a weight ratio of the first positive electrode active material to the second positive electrode active material is in a range of about 49:51 to about 20:80.

### Claim 9 (depends on 1)

The positive electrode as claimed in claim 1, wherein an amount of the conductive material is in a range of about 0.5 wt % to about 2 wt % based on a total weight of 100 wt % of the positive electrode active material layer.

### Claim 10 (depends on 1)

The positive electrode as claimed in claim 1, wherein a ratio of a weight of the conductive material to a total weight of the first positive electrode active material and the second positive electrode active material is in a range of about 1/99.5 to about 1/97.

### Claim 11 (depends on 1)

The positive electrode as claimed in claim 1, wherein the carbon-based material comprises at least one selected from among natural graphite, artificial graphite, carbon black, acetylene black, Ketjen black, carbon fiber, carbon nano-fiber, and carbon nano-tube.

### Claim 12 (depends on 1)

A rechargeable lithium battery comprising the positive electrode as claimed in claim 1.

### Claim 13 (depends on 12)

The rechargeable lithium battery as claimed in claim 12, wherein the rechargeable lithium battery has a capacity retention rate of equal to or greater than about 86% after 100 cycles of charge and discharge at about 0.33 C/1.0 C at about 40° C. to about 60° C.

### Claim 14

A method, comprising:
preparing a first positive electrode active material that comprises a lithium-nickel-based composite oxide;
performing a dry coating a lithium-nickel-based composite oxide with graphene to form a second positive electrode active material;
forming a slurry that comprises the first positive electrode active material, the second positive electrode active material, a conductive material, a binder, and a solvent; and
coating, drying, and pressing the slurry on a current collector,
wherein the method is a method of manufacturing a positive electrode.

### Claim 15 (depends on 14)

The method as claimed in claim 14, wherein the dry coating is performed at a rotation speed of about 2,000 rpm to about 3,000 rpm.

### Claim 16 (depends on 14)

The method as claimed in claim 14, wherein the dry coating is performed for about 5 minutes to about 15 minutes.

### Claim 17 (depends on 14)

The method as claimed in claim 14, wherein the dry coating comprises mixing the lithium-nickel-based composite oxide and the graphene.

### Claim 18 (depends on 14)

The method as claimed in claim 14, wherein, in forming the second positive electrode active material, a weight ratio of the lithium-nickel-based composite oxide to the graphene is in a range of about 99:1 to about 99.99:0.01.

### Claim 19 (depends on 14)

The method as claimed in claim 14, wherein, in forming the slurry, a weight ratio of the first positive electrode active material to the second positive electrode active material is in a range of about 49:51 to about 20:80.

### Claim 20 (depends on 14)

The method as claimed in claim 14, wherein, in forming the slurry, a ratio of a weight of the conductive material to a total weight of the first and second positive electrode active materials is in a range of about 1/99.5 to about 1/97.
