Zirconia sintered body
AssigneeNakashima Sangyo Co., Ltd.
InventorMikio Nakashima
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Abstract
A zirconia sintered body is disclosed, having a relative density of at least 99%, with a total Y2O3 content between 2.5 mol % and 6 mol %, and the remainder comprising ZrO2 and unavoidable impurities. In electron microscopic images, the area-averaged grain size of zirconia crystal grains is 0.4-0.9 μm, with less than 1% of grains below 0.1 μm and less than 1% above 2 μm. The area ratio of grains sized 0.1-0.5 μm (first region) is 5-80%, 0.8-2 μm (second region) is 5-80%, and 0.5-0.8 μm (third region) is 10-55%. The average Y2O3 concentration is 3.5-7.0 mol % in the second region (C2) and 1.7-5 mol % in the first region (C1), with ΔC/C2 (where ΔC=C2−C1) between 0.2 and 0.5. The fracture toughness, measured by the IF method, is 4.5-12 MPa·m05.
Claims13
A zirconia sintered body comprising:
- a Y2O3 content in a total composition of the zirconia sintered body is 2.5 mol % or greater and 6 mol % or less, and a remainder comprising ZrO2 and unavoidable impurities, and having a relative density of 99% or greater, wherein
- in an electron microscopic observation image of a microstructure of the sintered body,
- an area-averaged grain size of zirconia crystal grains is 0.4 μm or greater and 0.9 μm or less,
- an area ratio of zirconia crystal grains with a grain size of less than 0.1 μm and an area ratio of zirconia crystal grains with a grain size exceeding 2 μm are both less than 1%,
- an area ratio of a first region configured by zirconia crystal grains with a grain size of 0.1 μm or greater and less than 0.5 μm is 5% or greater and 80% or less,
- an area ratio of a second region configured by zirconia crystal grains with a grain size of 0.8 μm or greater and less than 2 μm is 5% or greater and 80% or less,
- an area ratio of a third region configured by zirconia crystal grains with a grain size of 0.5 μm or greater and less than 0.8 μm is 10% or greater and less than 55%,
- an average Y2O3 concentration C2 of the zirconia crystal grains forming the second region is 3.5 mol % or greater and 7.0 mol % or less,
- an average Y2O3 concentration C1 of the zirconia crystal grains forming the first region is 1.7 mol % or greater and 5 mol % or less, and when a difference in the Y2O3 concentrations is denoted as ΔC≡C2−C1, a value of ΔC/C2 is 0.2 or greater and 0.5 or less, and
- a fracture toughness value measured by IF method is 4.5 MPa·m0.5 or greater and 12 MPa·m0.5 or less.
Dependencies are inferred from the claim text.